408395
Dimethylammonium dimethylcarbamate
Synonym(s):
N-Methylmethanamine dimethylcarbamate, Dimcarb, Dimethylamine carbon dioxide complex
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About This Item
Linear Formula:
(CH3)2NH · (CH3)2NCOOH
CAS Number:
Molecular Weight:
134.18
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
4531667
Form:
liquid
form
liquid
refractive index
n20/D 1.454 (lit.)
bp
60-61 °C (lit.)
density
1.05 g/mL at 25 °C (lit.)
functional group
amine
SMILES string
CNC.CN(C)C(O)=O
InChI
1S/C3H7NO2.C2H7N/c1-4(2)3(5)6;1-3-2/h1-2H3,(H,5,6);3H,1-2H3
InChI key
JIYXHCMRGZVYMA-UHFFFAOYSA-N
General description
Dimethylammonium dimethylcarbamate (DIMCARB) is the carbamate salt of dimethylamine. It is widely used as solvent and extractant. It has been investigated as ionic liquid. DIMCARB is formed by the reaction of dimethylamine and carbon dioxide.
Application
Dimethylammonium dimethylcarbamate (DIMCARB) may be employed as an equivalent of dimethylamine, which on reaction with carboxylic acids affords N,N-dimethyl amides. It may be employed as ionic liquid for the synthesis of Cup-shaped calix[4]arenes bearing one or two ketocyanine fluorophore fragments at the wide rim of the macrocycle.
Ionic liquid primarily used as a solvent.
- For synthesis of calixarene-based ketocyanine fluorophores
- Distillation extraction of tannins from plant materials
- Electrodeposition of silver or of lead on glassy carbon and mercury film electrodes
- Synthesis of Ag and Au nanostructures
- Reusable reaction medium for synthesis of monoarylidene cyclopentanones
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Inhalation - Eye Dam. 1 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
3 - Flammable liquids
wgk
WGK 3
flash_point_f
55.4 °F - DIN 51758
flash_point_c
13 °C - DIN 51758
ppe
Eyeshields, Faceshields, Gloves
Regulatory Information
危险化学品
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Synthesis of calixarene-based ketocyanine fluorophores.
Matvieiev Y, et al.
Tetrahedron Letters, 52(30), 3922-3925 (2011)
Direct Catalytic Formation of Primary and Tertiary Amides from Non-Activated Carboxylic Acids, Employing Carbamates as Amine Source.
Tinnis F, et al.
Advanced Synthesis & Catalysis, 354(13), 2531-2536 (2012)
Lam Phan et al.
The Journal of organic chemistry, 73(1), 127-132 (2007-12-11)
Known liquids that can reversibly switch their polarity at atmospheric pressure are all prepared as mixtures of two liquid components; we now report a series of switchable-polarity solvents that consist, in their low-polarity form, of only a single liquid component
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 408395-25ML | 04061838349231 |