408689
Fmoc-Trp-OH
97%
Synonym(s):
Fmoc-L-tryptophan
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About This Item
Empirical Formula (Hill Notation):
C26H22N2O4
CAS Number:
Molecular Weight:
426.46
EC Number:
252-706-5
UNSPSC Code:
12352200
PubChem Substance ID:
Beilstein/REAXYS Number:
4216624
MDL number:
assay
97%
optical activity
[α]20/D −28°, c = 1 in DMF
impurities
<3% ethyl acetate
mp
182-185 °C (lit.)
SMILES string
OC(=O)[C@H](Cc1c[nH]c2ccccc12)NC(=O)OCC3c4ccccc4-c5ccccc35
InChI
1S/C26H22N2O4/c29-25(30)24(13-16-14-27-23-12-6-5-7-17(16)23)28-26(31)32-15-22-20-10-3-1-8-18(20)19-9-2-4-11-21(19)22/h1-12,14,22,24,27H,13,15H2,(H,28,31)(H,29,30)/t24-/m0/s1
InChI key
MGHMWKZOLAAOTD-DEOSSOPVSA-N
Application
Cyclic peptides used as tachykinin antagonists have been prepared from Fmoc-protected D- and L- tryptophans.
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B J Williams et al.
Journal of medicinal chemistry, 36(1), 2-10 (1993-01-08)
Twenty homodetic cyclic peptides based on the C-terminal sequence of substance P were prepared (Table I) by a combination of solid-phase techniques and cyclizations using azide coupling procedures. Incorporation of dipeptide mimics based on substituted gamma-lactams were used in some
He, J.X. et al.
Lett. Pept. Sci., 1, 25-25 (1994)