409413
2-(Triisopropylsilyl)-1,3-dithiane
97%
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About This Item
Empirical Formula (Hill Notation):
C13H28S2Si
CAS Number:
Molecular Weight:
276.58
UNSPSC Code:
12352100
PubChem Substance ID:
MDL number:
InChI
1S/C13H28S2Si/c1-10(2)16(11(3)4,12(5)6)13-14-8-7-9-15-13/h10-13H,7-9H2,1-6H3
SMILES string
CC(C)[Si](C(C)C)(C(C)C)C1SCCCS1
InChI key
RDHMCAVXJVTKDB-UHFFFAOYSA-N
assay
97%
mp
46-49 °C (lit.)
Application
A versatile acyl anion equivalent.
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
Regulatory Information
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Amos B Smith et al.
Journal of the American Chemical Society, 125(47), 14435-14445 (2003-11-20)
The development, application, and advantages of a one-flask multicomponent dithiane linchpin coupling protocol, over the more conventional stepwise addition of dithiane anions to electrophiles leading to the rapid, efficient, and stereocontrolled assembly of highly functionalized intermediates for complex molecule synthesis
Smith, A. B., III; Boldi, A. M.
Journal of the American Chemical Society, 119, 6925-6925 (1997)
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