416460
Diisopropylamine hydrochloride
99%
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About This Item
Linear Formula:
[(CH3)2CH]2NH·HCl
CAS Number:
Molecular Weight:
137.65
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
Assay
99%
mp
216-218 °C (lit.)
SMILES string
Cl.CC(C)NC(C)C
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2
Storage Class Code
11 - Combustible Solids
WGK
WGK 2
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Regulatory Information
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Antonio Ramirez et al.
Journal of the American Chemical Society, 128(31), 10326-10336 (2006-08-03)
Structural, kinetic, and computational studies reveal the mechanistic complexities of a lithium diisopropylamide (LDA)-mediated ester enolization. Hemilabile amino ether MeOCH2CH2NMe2, binding as an eta1 (ether-bound) ligand in the reactant and as an eta2 (chelating) ligand in the transition structure, accelerates
Da-Wei Fu et al.
Advanced materials (Deerfield Beach, Fla.), 23(47), 5658-5662 (2011-11-22)
A simple organic salt, diisopropylammonium chloride, shows the highest ferroelectric phase transition temperature among molecule-based ferroelectrics with a large spontaneous polarization, making it a candidate for practical technological applications.
Diisopropylamide and TMP turbo-Grignard reagents: a structural rationale for their contrasting reactivities.
David R Armstrong et al.
Angewandte Chemie (International ed. in English), 49(18), 3185-3188 (2010-03-31)
Kanwal Jit Singh et al.
Journal of the American Chemical Society, 128(42), 13753-13760 (2006-10-19)
Structural and mechanistic studies of the lithium diisopropylamide (LDA)-mediated anionic Fries rearrangements of aryl carbamates are described. Substituents at the meta position of the arene (H, OMe, F) and the dialkylamino moiety of the carbamate (Me(2)N, Et(2)N, and i-Pr(2)N) markedly
Mihai S Viciu et al.
Journal of the American Chemical Society, 132(18), 6361-6365 (2010-04-20)
Treatment of 2,6-difluoropyridine with lithium diisopropylamide in THF solution at -78 degrees C effects ortholithiation quantitatively. Warming the solution to 0 degrees C converts the aryllithium to 2-fluoro-6-(diisopropylamino)pyridine. Rate studies reveal evidence of a reversal of the ortholithiation and a
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