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Merck
CN

416703

Acenaphthylene

99%

Synonym(s):

Cyclopenta[de]naphthalene

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About This Item

Empirical Formula (Hill Notation):
C12H8
CAS Number:
208-96-8
Molecular Weight:
152.19
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
24865923
EC Number:
205-917-1
Beilstein/REAXYS Number:
774092
MDL number:
MFCD00003806
Assay:
99%
Form:
solid

Key Documents

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InChI key

HXGDTGSAIMULJN-UHFFFAOYSA-N

InChI

1S/C12H8/c1-3-9-4-2-6-11-8-7-10(5-1)12(9)11/h1-8H

SMILES string

c1cc2C=Cc3cccc(c1)c23

assay

99%

form

solid

bp

280 °C (lit.)

mp

78-82 °C (lit.)

density

0.899 g/mL at 25 °C (lit.)

Quality Level

100

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Application

Acenaphthylene has been used to investigate the photodimerization of acenaphthylene in micellar and hydrogel media.

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

251.6 °F - closed cup

flash_point_c

122.0 °C - closed cup

ppe

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
MKCP3591
MKBZ5351V
MKBG5263V
11303EE
065H3683

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An electron spin resonance study of the carbonization of the aromatic hydrocarbon acenaphthylene.
Singer LS and Lewis IC.
Carbon, 2(2), 115-120 (1964)
Durairajan Madhavan et al.
Photochemical & photobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology, 2(2), 95-97 (2003-04-01)
The photochemical dimerisation of acenaphthylene in the presence of various cation-exchanged bentonite clays has been studied. While the cis-dimer is the predominant product when smaller cations are present in the clay interlayer, the presence of heavier atoms in the clay
Kinetics and products of the gas-phase reactions of acenaphthene with hydroxyl radicals, nitrate radicals and ozone.
Zhou S and Wenger JC.
Atmospheric Environment, 72, 97-104 (2013)
M J Schocken et al.
Applied and environmental microbiology, 48(1), 10-16 (1984-07-01)
A Beijerinckia sp. and a mutant strain, Beijerinckia sp. strain B8/36, were shown to cooxidize the polycyclic aromatic hydrocarbons acenaphthene and acenaphthylene. Both organisms oxidized acenaphthene to the same spectrum of metabolites, which included 1-acenaphthenol, 1-acenaphthenone, 1,2-acenaphthenediol, acenaphthenequinone, and a
Shreedhar Bhat et al.
Molecules (Basel, Switzerland), 12(9), 2181-2189 (2007-10-27)
Many chemical reactions which are otherwise clean often lead to the formation of multiple products. Such products may be formed due to a lack of chemo-, regio- and/or stereoselectivity. For such reactions to be useful, one should be able to
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