417459
N-Methyl-1-(methylthio)-2-nitroethenamine
98%
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About This Item
Linear Formula:
O2NCH=C(SCH3)NHCH3
CAS Number:
Molecular Weight:
148.18
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
263-266-9
MDL number:
Product Name
N-Methyl-1-(methylthio)-2-nitroethenamine, 98%
InChI key
YQFHPXZGXNYYLD-ONEGZZNKSA-N
InChI
1S/C4H8N2O2S/c1-5-4(9-2)3-6(7)8/h3,5H,1-2H3/b4-3+
SMILES string
CN\C(SC)=C/[N+]([O-])=O
assay
98%
form
solid
mp
112-118 °C (lit.)
functional group
amine
nitro
thioether
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Application
(E) N-methyl-1-(methylthio)-2-nitroethenamine) (NMSM) may be used for the following syntheses:
- pyrano[2,3-c]pyrazol-6-amines
- 6-methoxy-N-methyl-3-nitro-4-nitromethyl-4H-chromen-2-amine
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
Regulatory Information
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6-Methoxy-N-methyl-3-nitro-4-nitromethyl-4H-chromen-2-amine.
Muthukumaran J, et al.
Acta Crystallographica Section E, Structure Reports Online, 67(5), 1276-1277 (2011)
Selvaraj Kanchithalaivan et al.
ACS combinatorial science, 15(12), 631-638 (2013-10-24)
An efficient one-pot four-component domino protocol for the combinatorial synthesis of novel 1,4-dihydropyrano[2,3-c]pyrazol-6-amines has been achieved. This transformation presumably occurs via cyclization-Knoevenagel condensation-Michael addition-tautomerism-intramolecular O-cyclization-elimination sequence of reactions. The significant features of this reaction include expedient one-pot process, short reaction
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