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418633

Tetrabenzyl pyrophosphate

Name: Tetrabenzyl pyrophosphate
Brand: ALDRICH

98%

Synonym(s):

Pyrophosphoric acid tetrabenzyl ester, Tetrabenzyl diphosphate

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About This Item

Linear Formula:

(C₆H₅CH₂O)₂P(O)OP(O)(OCH₂C₆H₅)₂

CAS Number:

990-91-0

Molecular Weight:

538.47

UNSPSC Code:

12352100

NACRES:

NA.22

PubChem Substance ID:

24866232

MDL number:

MFCD00051941

Beilstein/REAXYS Number:

2068292

Assay:

98%

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Properties

Quality Level

200

assay

98%

mp

63-66 °C (lit.)

functional group

phenyl, phosphate

storage temp.

−20°C

SMILES string

O=P(OCc1ccccc1)(OCc2ccccc2)OP(=O)(OCc3ccccc3)OCc4ccccc4

InChI

1S/C28H28O7P2/c29-36(31-21-25-13-5-1-6-14-25,32-22-26-15-7-2-8-16-26)35-37(30,33-23-27-17-9-3-10-18-27)34-24-28-19-11-4-12-20-28/h1-20H,21-24H2

InChI key

NSBNXCZCLRBQTA-UHFFFAOYSA-N

Description

Application

Tetrabenzyl pyrophosphate may be employed for the following studies:

Fabrication of Pb²⁺-selective membrane electrodes.
Preparation of synthetic nucleotides, phosphates of the 3,6-dideoxyhexoses.
As phosphorylating reagent for the synthesis of Und-PP-Bac (undecaprenyl pyrophosphate = Und-PP; Bac = unusual sugar bacillosamine).

pictograms

GHS05

signalword

Danger

hcodes

H314

pcodes

P260 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P363

Hazard Classifications

Skin Corr. 1B

Storage Class

8A - Combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

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Certificates of Analysis (COA)

Lot/Batch Number

0000473743

0000226897

0000203676

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Tetrabenzyl pyrophosphate as a new class of neutral carrier responsive to lead ion.

D Xu et al.

Talanta, 51(2), 365-371 (2008-10-31)

Tetrabenzyl pyrophosphate and diphenylphosphinic anhydride, with two phosphoryl groups (PO) as ligating sites, can be used as novel ionophores to make Pb(2+)-selective membrane electrodes. A good result was obtained with tetrabenzyl pyrophosphate, and the electrode based on this ionophore and

The Journal of Organic Chemistry, 59, 2279-2279 (1994)

[Synthesis of cytidine diphosphate-3,6-dideoxyhexoses--donors of glycosyl residues in the biosynthesis of O-specific polysaccharides of Salmonella of serogroups A, B and C].

N S Utkina et al.

Bioorganicheskaia khimiia, 15(10), 1375-1383 (1989-10-01)

Interaction of lithium alcoholates of 2,4-di-O-benzoates of paratose and abequose with tetrabenzyl pyrophosphate gave alpha-phosphates of the 3,6-dideoxyhexoses, further converted into the corresponding cytidine-5'-diphosphate derivatives. These synthetic nucleotides were shown to participate in the biosynthesis of the O-specific polysaccharides for

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Global Trade Item Number

SKU	GTIN
418633-1G	04061826663271