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Merck
CN

418943

Sigma-Aldrich

2,2′-[4-(2-Hydroxyethylamino)-3-nitrophenylimino]diethanol

98%

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About This Item

Linear Formula:
HOCH2CH2NHC6H3(NO2)N(CH2CH2OH)2
CAS Number:
Molecular Weight:
285.30
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
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Assay

98%

mp

108-111 °C (lit.)

solubility

water: soluble(lit.)

SMILES string

OCCNc1ccc(cc1[N+]([O-])=O)N(CCO)CCO

InChI

1S/C12H19N3O5/c16-6-3-13-11-2-1-10(9-12(11)15(19)20)14(4-7-17)5-8-18/h1-2,9,13,16-18H,3-8H2

InChI key

MIWUTEVJIISHCP-UHFFFAOYSA-N

General description

2,2′-[4-(2-Hydroxyethylamino)-3-nitrophenylimino]diethanol (HC Blue No.2) is a water-soluble purple dye.

Application

2,2′-[4-(2-Hydroxyethylamino)-3-nitrophenylimino]diethanol may be employed to improve the visibility of self-healing ureidopyrimidinone (UPy) hydrogel (poly(ethylene glycol) containing bifunctional UDP groups).

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

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Species comparisons regarding comparative metabolism of two structurally similar phenylenediamines (HC Blue 1 and HC Blue 2).
F Kari et al.
Progress in clinical and biological research, 340D, 305-314 (1990-01-01)
C M Burnett et al.
Food and chemical toxicology : an international journal published for the British Industrial Biological Research Association, 25(9), 703-707 (1987-09-01)
A number of hair-dye chemicals that have given positive results in various short-term mutagenicity tests have shown no clear evidence of carcinogenicity in animal bioassays. Commercial HC Blue No. 1 and its analogues HC Red No. 3 and HC Blue
National Toxicology Program technical report series, 293, 1-192 (1985-08-01)
Toxicology and carcinogenesis studies of HC Blue No. 2 (approximately 98% pure), a semipermanent hair dye, were conducted by administering the test chemical in feed for 103 weeks to groups of 50 F344/N rats of each sex and for 104
F W Kari et al.
Toxicology, 56(2), 155-165 (1989-06-01)
Toxicology and carcinogenesis studies of 2 structurally-related p-phenylenediamines, HC Blue No. 1, and HC Blue No. 2 were conducted by administering each chemical in feed for 103 weeks to both sexes of Fischer 344/N rats and B6C3F1 (C57BL/6N x C3H/HEN)
F W Kari et al.
Cell biology and toxicology, 6(2), 139-155 (1990-04-01)
Previous studies indicated that HC Blue 1 induced heptocellular carcinomas in B6C3F1 mice whereas the structurally similar nitroaromatic amine HC Blue 2 did not. In an attempt to elucidate the biochemical mechanisms responsible for their different carcinogenic potencies, comparative metabolism

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