425117
Ethyl 2-butynoate
98%
Synonym(s):
Ethyl tetrolate
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About This Item
Linear Formula:
CH3C≡CC(O)OCH2CH3
CAS Number:
Molecular Weight:
112.13
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
224-395-6
Beilstein/REAXYS Number:
1744948
MDL number:
Assay:
98%
Form:
liquid
Quality Level
assay
98%
form
liquid
refractive index
n20/D 1.436 (lit.)
bp
160-161 °C/730 mmHg (lit.)
density
0.962 g/mL at 25 °C (lit.)
functional group
ester
SMILES string
CCOC(=O)C#CC
InChI
1S/C6H8O2/c1-3-5-6(7)8-4-2/h4H2,1-2H3
InChI key
FCJJZKCJURDYNF-UHFFFAOYSA-N
General description
Ethyl 2-butynoate, a 2-alkynoate is a methanogenesis inhibitor. It is an electron deficient internal alkyne that has been reported to undergo codimerization with alkenes to form 1,3-dienes catalyzed by rhodium(I)/H8-BINAP complex. The annulation of thioamides with ethyl 2-butynoate catalyzed by tri-n-butylphosphine to form thiazolines has been investigated.
Application
Ethyl 2-butynoate was used in the study of its effect on in vitro degradation and microbial biomass production.
It may be used in the synthesis of the following:
It may be used in the synthesis of the following:
- 3-ethyl, 1-methyl 1-(2-nitrophenyl)-cyclopent-3-ene-1,3-dicarboxylate
- tricyclic aziridine derivatives
- alkenylsilanols
signalword
Warning
target_organs
Respiratory system
wgk
WGK 3
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
hcodes
Hazard Classifications
Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
Storage Class
3 - Flammable liquids
flash_point_f
134.6 °F
flash_point_c
57 °C
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Efficient and stereoselective cross-coupling with highly substituted alkenylsilanols.
Denmark SE and Pan W.
Journal of Organometallic Chemistry, 653(1), 98-104 (2002)
Dichloro [TADDOLato (2-)-O,O'] titanium/Dichlorobis [1-methylethoxy] titanium-Mediated, Highly Diastereo-and Enantioselective Additions of Silyl Enol Ethers to Nitro Olefins and [3+ 2] Cycloadditions of Primary Adducts to Acetylenes.
Seebach D, et al.
Helvetica Chimica Acta, 82(11), 1829-1842 (1999)
Bing Liu et al.
The Journal of organic chemistry, 67(13), 4595-4598 (2002-06-22)
The annulation of thioamides with 2-alkynoates and 2,3-dienoates under the catalysis of tri-n-butylphosphine was described. The annulation reaction provided a new entry to thiazolines, particularly those with 2-aryl substituents.
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 425117-10G | 04061832103914 |
| 425117-1G | 04061832103921 |