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Merck
CN

427128

Gallium(III) chloride

beads, anhydrous, ≥99.999% trace metals basis

Synonym(s):

Gallium trichloride

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About This Item

Linear Formula:
GaCl3
CAS Number:
Molecular Weight:
176.08
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
236-610-0
MDL number:
Assay:
≥99.999% trace metals basis
Grade:
anhydrous
Form:
beads
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grade

anhydrous

Quality Level

vapor pressure

1 mmHg ( 48 °C)

assay

≥99.999% trace metals basis

form

beads

reaction suitability

reagent type: catalyst
core: gallium

impurities

≤10.0 ppm Trace Metal Analysis

density

2.47 g/mL at 25 °C (lit.)

SMILES string

Cl[Ga](Cl)Cl

InChI

1S/3ClH.Ga/h3*1H;/q;;;+3/p-3

InChI key

UPWPDUACHOATKO-UHFFFAOYSA-K

General description

Gallium(III) chloride is prepared by reacting Ga metal with Cl2 or HCl in N2 at 200oC.1

Application

Catalyst for a number of transformations such as the ring opening and recyclization of epoxides or the trimerization of alkynes.

Features and Benefits

Lower-temperature solvothermal techniques using GaCl3 and NaN3 or Li3N result in nanocrystalline GaN.
Radical mediator and catalyst in a number of organic bond formation reactions.

Packaging

product is packed in vials


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pictograms

Corrosion

signalword

Danger

hcodes

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B

supp_hazards

Storage Class

8B - Non-combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges



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Chien-Hui Syu et al.
The Science of the total environment, 759, 143943-143943 (2020-12-20)
The emerging contaminants gallium (Ga) and indium (In) are extensively used in advanced industries and are considered as toxic to humans. Limited information is available on the dynamics of Ga and In in soil-upland crop systems. Therefore, this study aimed
Tiina Ujula et al.
Molecular imaging and biology : MIB : the official publication of the Academy of Molecular Imaging, 12(3), 259-268 (2009-10-03)
The aim of the study was to compare (68)Ga-chloride with 2-[(18)F]fluoro-2-deoxy-D: -glucose (FDG) for the imaging of pancreatic xenografts. Rats with subcutaneous human pancreatic adenocarcinoma xenografts were evaluated in vivo by dynamic positron emission tomography (PET) and ex vivo by
Amir R Jalilian et al.
Acta pharmaceutica (Zagreb, Croatia), 59(4), 421-429 (2009-11-19)
beta-Human chorionic gonadotropin (beta-hCG) was successively labeled with [(67)Ga]-gallium chloride after conjugation with freshly prepared diethylenetriaminepentaacetic acid dianhydride (ccDTPA). After solid phase purification of the radiolabeled hormone, high performance liquid chromatography showed radiochemical purity higher than 95 % under optimized



Global Trade Item Number

SKUGTIN
427128-100G04061838139610
427128-5G04061832104454
427128-25G04061832104447