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Merck
CN

434787

Polybutadiene

average Mn ~3,000 by VPO

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About This Item

Linear Formula:
(CH2CH=CHCH2)n
CAS Number:
PubChem Substance ID:
UNSPSC Code:
12162002
MDL number:
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InChI

1S/C4H8/c1-3-4-2/h3-4H,1-2H3/b4-3+

InChI key

IAQRGUVFOMOMEM-ONEGZZNKSA-N

description

peroxide number <= 10 mval/kg

form

viscous liquid

mol wt

average Mn ~3,000 by VPO

composition

cis-1,4, 75% , trans-1,4, 24% , vinyl, 1%

refractive index

n20/D 1.524

viscosity

2,700-3,000 mPa.s(20 °C)(lit.)

mp

−6 °C

acid number

≤0.3 mg KOH/g

iodine value

420‑480 g/100g

transition temp

pour point ~−50 °C

solubility

aliphatic hydrocarbons: soluble

density

0.9 g/mL at 25 °C (lit.)

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Application

Co-reactant for air curing coatings.

Features and Benefits

Low viscosity liquid that undergoes polymerization in the presence of oxygen and free radical generators. Unsaponifiable drying oil. Improves water and chemical resistance.

Storage Class

10 - Combustible liquids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

Regulatory Information

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Alexandra Sperschneider et al.
ACS nano, 4(10), 5609-5616 (2010-09-17)
We report on the quasi in situ scanning force microscopy nanotomography which proved to be a key method to effectively obtain a three-dimensional (3D) microdomain structure of a complex ABC triblock morphology. As an example, we studied polybutadiene-block-poly(2-vinyl pyridine)-block-poly(tert-butyl methacrylate)
Dong Wu et al.
Journal of the American Chemical Society, 132(45), 15936-15938 (2010-10-28)
Single-molecule force spectroscopy is used to observe the irreversible extension of a gem-dibromocyclopropane (gDBC)-functionalized polybutadiene under tension, a process akin to polymer necking at a single-molecule level. The extension of close to 28% in the contour length of the polymer
Mechanochemistry: Demonstrated leverage.
Roman Boulatov
Nature chemistry, 5(2), 84-86 (2013-01-25)
Yohan van de Looij et al.
NMR in biomedicine, 25(1), 93-103 (2011-05-28)
Diffusion tensor imaging (DTI) was used to study traumatic brain injury. The impact-acceleration trauma model was used in rats. Here, in addition to diffusivities (mean, axial and radial), fractional anisotropy (FA) was used, in particular, as a parameter to characterize
Aleer M Yol et al.
Journal of the American Society for Mass Spectrometry, 24(1), 74-82 (2012-11-30)
[M + Ag](+) ions from cyclic and linear polystyrenes and polybutadienes, formed by matrix-assisted laser desorption ionization (MALDI), give rise to significantly different fragmentation patterns in tandem mass spectrometry (MS(2)) experiments. In both cases, fragmentation starts with homolytic cleavage at

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