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Merck
CN

440442

O-(Trimethylsilyl)hydroxylamine

technical grade, 90%

Synonym(s):

Aminoxytrimethylsilane

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About This Item

Linear Formula:
(CH3)3SiONH2
CAS Number:
Molecular Weight:
105.21
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
2035893
Assay:
90%
Form:
liquid
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InChI

1S/C3H11NOSi/c1-6(2,3)5-4/h4H2,1-3H3

SMILES string

C[Si](C)(C)ON

InChI key

AEKHNNJSMVVESS-UHFFFAOYSA-N

grade

technical grade

assay

90%

form

liquid

Quality Level

bp

98-100 °C (lit.)

density

0.86 g/mL at 25 °C (lit.)

storage temp.

2-8°C

Related Categories

General description

O-(Trimethylsilyl)hydroxylamine is an O-substituted hydroxylamine. It is formed as an intermediate during the trimethylsilyl chloride catalyzed synthesis of α-branched amines.

Application

O-(Trimethylsilyl)hydroxylamine may be used for the preparation of O-trimethylsilyl oxime ethers.

pictograms

FlameCorrosion

signalword

Danger

hcodes

Hazard Classifications

Flam. Liq. 2 - Skin Corr. 1B

Storage Class

3 - Flammable liquids

wgk

WGK 3

flash_point_f

53.6 °F - closed cup

flash_point_c

12 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

Regulatory Information

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Ying Fu et al.
Organic & biomolecular chemistry, 10(38), 7669-7672 (2012-08-14)
A general procedure for the nucleophilic addition of organozinc halides with nitrones in the presence of trimethylsilyl chloride has been developed. Trimethylsilyl chloride was found to be both an indispensable reaction promoter and a ready hydroxylamine protective agent in these
Chemoselective addition of organometallics to oxime ethers.
Tavakol H,et al.
Journal of Organometallic Chemistry, 692(10), 1924-1927 (2007)

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