443239
5-Chloro-2-thiophenecarboxaldehyde
97%
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About This Item
Empirical Formula (Hill Notation):
C5H3ClOS
CAS Number:
Molecular Weight:
146.59
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
Assay
97%
refractive index
n20/D 1.604 (lit.)
bp
99 °C/21 mmHg (lit.)
density
1.376 g/mL at 25 °C (lit.)
functional group
aldehyde
chloro
SMILES string
[H]C(=O)c1ccc(Cl)s1
InChI
1S/C5H3ClOS/c6-5-2-1-4(3-7)8-5/h1-3H
InChI key
VWYFITBWBRVBSW-UHFFFAOYSA-N
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General description
5-Chloro-2-thiophenecarboxaldehyde is a thiophene derivative.
Application
5-Chloro-2-thiophenecarboxaldehyde may be used for synthesis of 2-heteroaryl-α-methyl-5-benzoxazoleacetic acids and N,N′-bis[(E)-(5-chloro-2-thienyl)methylidene]ethane-1,2-diamine
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral
Storage Class Code
10 - Combustible liquids
WGK
WGK 3
Flash Point(F)
208.4 °F - closed cup
Flash Point(C)
98 °C - closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Regulatory Information
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M da Consolação et al.
Journal of medicinal chemistry, 18(11), 1159-1161 (1975-11-01)
Lapachol [2-hydroxy-3-(3-methyl-2-butenyl)-1,4-naphthoquinone] and its analogs [2-(3,7-dimethyl-2,6-octadienyl)-3-hydroxy-1,4-naphthoquinone and 2-(3,3-dibromo-2-propenyl)-3-hydroxy-1,4-naphthoquinone] have been described, among almost a hundred synthesized analogs, as active against rat tumor Walker 256 carcinosarcoma. The acetylglucosylation of lapachol results in a compound which extends lapachol activity becoming effective against
N, N'-Bis [(E)-(5-chloro-2-thienyl) methylidene] ethane-1, 2-diamine.
Prasath R, et al.
Acta Crystallographica Section E, Structure Reports Online, 66(11), o2883-o2883 (2010)
Synthesis of 6-(Thienylmethylene)penam Sulfones and their ?-Lactamase Inhibitory Activities.
Kim DH, et al.
Yakhak Hoechi, 51(6) (2007)
(E)-4-[(5-Chloro-2-thienyl) methyleneamino]-1, 5-dimethyl-2-phenyl-1H-pyrazol-3 (2H)-one.
Zhang C-N, et al.
Acta Crystallographica Section E, Structure Reports Online, 63(2), o912-o913 (2007)
Synthesis and antiinflammatory activity of some 2-heteroaryl-alpha-methyl-5-benzoxazoleacetic acids.
D W Dunwell et al.
Journal of medicinal chemistry, 18(11), 1158-1159 (1975-11-01)
The syntheses of eight of the title compounds are described. The compounds possessed activity comparable with that of the previously tested 2-substituted phenyl analogs in the carrageenan-induced rat paw edema test.
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