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Merck
CN

44696

2-(Dimethylaminomethyl)ferrocen-1-yl-palladium(II) chloride Dinorbornylphosphine Complex

≥97.0% (C)

Synonym(s):

Chloro-2-(dimethylaminomethyl)-ferrocen-1-yl-(dinorbornylphosphine)palladium, SK-CC02-A

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About This Item

Empirical Formula (Hill Notation):
C27H39ClFeNPPd
CAS Number:
Molecular Weight:
606.30
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352300
MDL number:
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assay

≥97.0% (C)

form

powder

reaction suitability

core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Cross Couplings, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst

mp

~156 °C (dec.), ~156 °C

SMILES string

[Fe].[CH]1[CH][CH][CH][CH]1.CN(C)C[C]2[CH][CH][CH][C]2[Pd]Cl.[H][C@]34CC[C@]([H])(C3)C(C4)PC5C[C@]6([H])CC[C@@]5([H])C6

InChI

1S/C14H23P.C8H11N.C5H5.ClH.Fe.Pd/c1-3-11-5-9(1)7-13(11)15-14-8-10-2-4-12(14)6-10;1-9(2)7-8-5-3-4-6-8;1-2-4-5-3-1;;;/h9-15H,1-8H2;3-5H,7H2,1-2H3;1-5H;1H;;/q;;;;;+1/p-1/t9-,10+,11+,12-,13?,14?;;;;;

InChI key

WLPBCKROBGAVNZ-HHYUVNRKSA-M

General description

sold in collaboration with Solvias AG

Packaging

Bottomless glass bottle. Contents are inside inserted fused cone.

Other Notes

Catalyst for CN and CC coupling, especially Buchwald-Hartwig Amination; Heck and Suzuki coupling reactions are also possible. The catalyst is stable to air


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Articles

Palladacyclic catalysts by Bedford's group facilitate coupling reactions with low catalyst loadings and challenging aryl chlorides.