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448427

(4R)-2-Hydroxy-5,5-dimethyl-4-phenyl-1,3,2-dioxaphosphorinan 2-oxide

Name: (4<I>R</I>)-2-Hydroxy-5,5-dimethyl-4-phenyl-1,3,2-dioxaphosphorinan 2-oxide
Brand: ALDRICH

98%

Synonym(s):

(2R,4R)-5,5-Dimethyl-2-hydroxy-4-phenyl-1,3,2-dioxaphosphorinan 2-oxide, (R)-(−)-2-Hydroxy-5,5-dimethyl-4-phenyl-1,3,2-dioxaphosphorinane 2-oxide

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About This Item

Empirical Formula (Hill Notation):

C₁₁H₁₅O₄P

CAS Number:

98674-80-7

Molecular Weight:

242.21

UNSPSC Code:

12352005

NACRES:

NA.22

PubChem Substance ID:

24868406

MDL number:

MFCD00044976

Beilstein/REAXYS Number:

4294714

Assay:

98%

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Properties

Quality Segment

200

assay

98%

optical activity

[α]20/D −62°, c = 0.5 in methanol

impurities

<5% water

mp

224-227 °C (lit.)

functional group

phenyl, phosphate

storage temp.

2-8°C

SMILES string

CC1(C)COP(O)(=O)O[C@@H]1c2ccccc2

InChI

1S/C11H15O4P/c1-11(2)8-14-16(12,13)15-10(11)9-6-4-3-5-7-9/h3-7,10H,8H2,1-2H3,(H,12,13)/t10-/m1/s1

InChI key

PSZSDCWNBXVDFG-SNVBAGLBSA-N

Description

Application

(4R)-2-Hydroxy-5,5-dimethyl-4-phenyl-1,3,2-dioxaphosphorinan 2-oxide can be used:

As a reactant in the phosphoalkoxylation of aromatic enones.
As a chiral resolving agent in the resolution of amino acids, amines, and amino alcohols.

pictograms

GHS07

signalword

Warning

hcodes

H315,H319,H335

pcodes

P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c