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Merck
CN

450103

Yttrium(III) chloride

AnhydroBeads™, −10 mesh, 99.99% trace metals basis

Synonym(s):

Yttrium trichloride

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About This Item

Linear Formula:
YCl3
CAS Number:
10361-92-9
Molecular Weight:
195.26
NACRES:
NA.23
PubChem Substance ID:
24868533
UNSPSC Code:
12352302
EC Number:
233-801-0
MDL number:
MFCD00011470
Assay:
99.99% trace metals basis
Grade:
synthesis grade

Key Documents

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Product Name

Yttrium(III) chloride, AnhydroBeads™, −10 mesh, 99.99% trace metals basis

InChI key

PCMOZDDGXKIOLL-UHFFFAOYSA-K

InChI

1S/3ClH.Y/h3*1H;/q;;;+3/p-3

SMILES string

Cl[Y](Cl)Cl

grade

synthesis grade

product line

AnhydroBeads™

assay

99.99% trace metals basis

reaction suitability

core: yttrium

impurities

≤150.0 ppm Trace Rare Earth Analysis

particle size

−10 mesh

mp

721 °C (lit.)

density

2.67 g/mL at 25 °C (lit.)

application(s)

electroplating
material synthesis precursor

Quality Level

100

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Application

Used to prepare yttrium alkyl alkoxide complexes under strictly anhydrous conditions.

Features and Benefits

Will react with potassium alkoxotitanates to form precursors to novel titanium-containing ceramics

Legal Information

AnhydroBeads is a trademark of Sigma-Aldrich Co. LLC

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Danger

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Sens. 1B

Storage Class

13 - Non Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
0000521759
0000521758
0000521759
0000521758
0000507627

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Evans, W.J. et al.
Organometallics, 15, 1351-1351 (1996)
Acceleration of the substitution of silanes with Grignard reagents by using either LiCl or YCl3/MeLi.
Naoki Hirone et al.
Angewandte Chemie (International ed. in English), 49(42), 7762-7764 (2010-09-08)
S Hirano et al.
Toxicology and applied pharmacology, 121(2), 224-232 (1993-08-01)
Although radioactive yttrium (Y) has been used for medical treatment, little attention has been directed toward the toxicity of Y. We report time-course and dose-related changes in tissue distribution, subcellular localization, clearance, and acute toxicity of iv-injected yttrium chloride (YCl3)
F Zhang et al.
Physical review letters, 101(14), 148101-148101 (2008-10-15)
Negatively charged globular proteins in solution undergo a condensation upon adding trivalent counterions between two critical concentrations C and C, C <C. This reentrant condensation behavior above C is caused by short-ranged electrostatic interactions between multivalent cations and acidic residues
Jérôme Hannedouche et al.
Chemical communications (Cambridge, England), (30)(30), 3552-3554 (2008-07-26)
A facile method for the preparation of highly active and enantioselective yttrium precatalysts for asymmetric hydroamination of gem-disubstituted aminoalkenes, from the combination of YCl(3) or YCl(3)(THF)(3.5) with ligand (R)- and n-BuLi is described.
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