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Merck
CN

450898

Gallium(III) chloride

anhydrous, beads, −10 mesh, 99.99% trace metals basis

Synonym(s):

Gallium trichloride

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About This Item

Linear Formula:
GaCl3
CAS Number:
13450-90-3
Molecular Weight:
176.08
NACRES:
NA.23
PubChem Substance ID:
24868554
UNSPSC Code:
12352302
EC Number:
236-610-0
MDL number:
MFCD00011018
Assay:
99.99% trace metals basis
Grade:
anhydrous
Form:
beads

Key Documents

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InChI key

UPWPDUACHOATKO-UHFFFAOYSA-K

InChI

1S/3ClH.Ga/h3*1H;/q;;;+3/p-3

SMILES string

Cl[Ga](Cl)Cl

grade

anhydrous

vapor pressure

1 mmHg ( 48 °C)

assay

99.99% trace metals basis

form

beads

reaction suitability

reagent type: catalyst
core: gallium

impurities

≤150.0 ppm Trace Metal Analysis

particle size

−10 mesh

Quality Level

100

density

2.47 g/mL at 25 °C (lit.)

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Application

Catalyst for a number of transformations such as the ring opening and recyclization of epoxides or the trimerization of alkynes.

Features and Benefits

Lower-temperature solvothermal techniques using GaCl3 and NaN3 or Li3N result in nanocrystalline GaN.
Radical mediator and catalyst in a number of organic bond formation reactions.

Packaging

product is packed in vials

pictograms

Corrosion
GHS05

signalword

Danger

hcodes

H314

Hazard Classifications

Skin Corr. 1B

supp_hazards

EUH014

Storage Class

8A - Combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

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Certificates of Analysis (COA)

Lot/Batch Number
MKBZ5957V
MKBZ5958V
MKBZ5960V
MKBW4978V
MKBW4977V

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Kellogg, R.M.
Chemtracts, 16, 79-79 (2003)
Morten Persson et al.
Nuclear medicine and biology, 39(4), 560-569 (2011-12-17)
The urokinase-type plasminogen activator receptor (uPAR) is a well-established biomarker for tumor aggressiveness and metastatic potential. DOTA-AE105 and DOTA-AE105-NH(2) labeled with (64)Cu have previously been demonstrated to be able to noninvasively monitor uPAR expression using positron emission tomography (PET) in
Vijay Kumar et al.
Nuclear medicine and biology, 38(3), 393-398 (2011-04-16)
(67)Ga citrate has been extensively used to detect infection and inflammation since 1971. However, its clinical utility is compromised due to several limitations. The present project explored whether (68)Ga-apo-transferrin ((68)Ga-TF), when prepared in vitro, is a useful agent for positron
Catherine S Branch et al.
Journal of the American Chemical Society, 124(47), 14156-14161 (2002-11-21)
We have previously proposed that the Hg(arene)(2)(GaCl(4))(2) catalyzed H/D exchange reaction of C(6)D(6) with arenes occurs via an electrophilic aromatic substitution reaction in which the coordinated arene protonates the C(6)D(6). To investigate this mechanism, the kinetics of the Hg(C(6)H(5)Me)(2)(GaCl(4))(2) catalyzed
Amir R Jalilian et al.
Acta pharmaceutica (Zagreb, Croatia), 59(4), 421-429 (2009-11-19)
beta-Human chorionic gonadotropin (beta-hCG) was successively labeled with [(67)Ga]-gallium chloride after conjugation with freshly prepared diethylenetriaminepentaacetic acid dianhydride (ccDTPA). After solid phase purification of the radiolabeled hormone, high performance liquid chromatography showed radiochemical purity higher than 95 % under optimized
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