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Merck
CN

451398

Zinc bromide

AnhydroBeads™, −10 mesh, 99.999% trace metals basis

Synonym(s):

Zinc dibromide

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About This Item

Linear Formula:
ZnBr2
CAS Number:
7699-45-8
Molecular Weight:
225.20
PubChem Substance ID:
24868627
eCl@ss:
38150410
UNSPSC Code:
12352302
NACRES:
NA.23
EC Number:
231-718-4
MDL number:
MFCD00011294
Assay:
99.999% trace metals basis
Grade:
synthesis grade
Solubility:
diethyl ether: slightly soluble(lit.), ethanol: very soluble(lit.)

Key Documents

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InChI key

VNDYJBBGRKZCSX-UHFFFAOYSA-L

InChI

1S/2BrH.Zn/h2*1H;/q;;+2/p-2

SMILES string

Br[Zn]Br

grade

synthesis grade

product line

AnhydroBeads™

assay

99.999% trace metals basis

reaction suitability

core: zinc, reagent type: catalyst

impurities

≤15.0 ppm Trace Metal Analysis

particle size

−10 mesh

bp

~670 °C/1 atm (lit.)

mp

394 °C (lit.)

solubility

diethyl ether: slightly soluble(lit.), ethanol: very soluble(lit.)

application(s)

electroplating
material synthesis precursor

Quality Level

100

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Related Categories

Application

Optimal catalyst for stereospecific and regioselective reaction of silacyclopropanes with carbonyl compounds.

Legal Information

AnhydroBeads is a trademark of Sigma-Aldrich Co. LLC

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Danger

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Skin Corr. 1B - Skin Sens. 1

Storage Class

8B - Non-combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

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Certificates of Analysis (COA)

Lot/Batch Number
0000461367
0000461365
0000461365
0000461367
0000212218

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Franz, A.K. Woerpel, K.A.
Journal of the American Chemical Society, 121, 949-949 (1999)
Yu Sung Chun et al.
Organic letters, 11(15), 3414-3417 (2009-07-04)
The in situ generated Blaise reaction intermediate, a zinc bromide complex of beta-enaminoester, reacts with various unactivated terminal alkynes and an internal alkyne under mild conditions to afford alpha-vinylated beta-enaminoesters in good to excellent yields.
Biswajit Kalita et al.
Chemical communications (Cambridge, England), (36)(36), 4291-4293 (2008-09-20)
Benzylic and allylic hydrocarbons are selectively converted to the corresponding sulfonamides by a ZnBr2-H2O-catalyzed reaction with PhI=NTs; saturated adamantane is aminosulfonated at the tertiary C-H bond.
J R Baker et al.
Organic letters, 9(1), 45-48 (2006-12-29)
[reaction: see text] A key structural feature of the Neocarzinostatin chromophore is a reactive epoxydiyne. We present here a new method for the preparation of epoxydiynes by the addition of an allenyl zinc bromide to a propargylic ketone.
Yasuhiro Inui et al.
Chemical & pharmaceutical bulletin, 57(10), 1158-1160 (2009-10-06)
Asymmetric intermolecular hydroacylation between salicylaldehyde (1) and 1,5-hexadiene (2) using a combination of [RhCl(C(8)H(14))(2)](2) (0.10 eq), (S)-BINAP (0.10 eq), and ZnBr(2) (0.20 eq) afforded an enantiomerically enriched hydroacylated product iso-3 of 84% ee, along with an achiral product normal-3.
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