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452823

(+)-Bis[(R)-1-phenylethyl]amine

Name: (+)-Bis[(<I>R</I>)-1-phenylethyl]amine
Brand: ALDRICH

99%

Synonym(s):

(+)-Bis[(R)-α-methylbenzyl]amine, [R-(R*,R*)]-(+)-Bis(α-methylbenzyl)amine

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About This Item

Linear Formula:

[C₆H₅CH(CH₃)]₂NH

CAS Number:

23294-41-9

Molecular Weight:

225.33

UNSPSC Code:

12352116

NACRES:

NA.22

PubChem Substance ID:

24868728

MDL number:

MFCD00243088

Beilstein/REAXYS Number:

3590931

Assay:

99%

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Properties

Quality Segment

100

assay

99%

optical activity

[α]20/D +199.0°, neat

optical purity

ee: ≥99% (GLC)

refractive index

n20/D 1.5523 (lit.)

bp

86 °C/0.05 mmHg (lit.)

density

0.985 g/mL at 25 °C (lit.)

functional group

amine, phenyl

SMILES string

C[C@@H](N[C@H](C)c1ccccc1)c2ccccc2

InChI

1S/C16H19N/c1-13(15-9-5-3-6-10-15)17-14(2)16-11-7-4-8-12-16/h3-14,17H,1-2H3/t13-,14-/m1/s1

InChI key

NXLACVVNHYIYJN-ZIAGYGMSSA-N

Description

Application

(+)-Bis[(R)-1-phenylethyl]amine can be used:

In the synthesis of β-amino acids.
In the preparation of chiral C(19)-C(26) and C(27)-C(32) moieties of scytophycin C.
To induce enantioselectivity in the deprotonation of prochiral ketones.
As a starting material for the synthesis of chiral phenolate ligands through Mannich condensation reaction.
In the synthesis of chiral phosphoramidite ligands.
To prepare chiral cyclic isoimidium salts, which are further used to synthesize chiral lactones through Diels-Alder reaction.

pictograms

GHS07

signalword

Warning

hcodes

H315,H319,H335

pcodes

P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

10 - Combustible liquids

flash_point_f

>235.4 °F - closed cup

flash_point_c

> 113 °C - closed cup

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

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