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453048

Dichlorobis(tri-o-tolylphosphine)palladium(II)

greener alternative

Greener Alternative

97%, solid

Synonym(s):

PdCl2[P(o-Tol)3]2

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About This Item

Linear Formula:
[(CH3C6H4)3P]2PdCl2
CAS Number:
40691-33-6
Molecular Weight:
786.06
UNSPSC Code:
12161600
PubChem Substance ID:
24868751
NACRES:
NA.22
MDL number:
MFCD00274659
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Product Name

Dichlorobis(tri-o-tolylphosphine)palladium(II), 97%

Quality Segment

200

assay

97%

form

solid

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Cross Couplings, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
core: palladium

greener alternative product characteristics

Catalysis
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sustainability

Greener Alternative Product

mp

280 °C (dec.) (lit.)

greener alternative category

Aligned

SMILES string

Cl[Pd]Cl.Cc1ccccc1P(c2ccccc2C)c3ccccc3C.Cc4ccccc4P(c5ccccc5C)c6ccccc6C

InChI

1S/2C21H21P.2ClH.Pd/c2*1-16-10-4-7-13-19(16)22(20-14-8-5-11-17(20)2)21-15-9-6-12-18(21)3;;;/h2*4-15H,1-3H3;2*1H;/q;;;;+2/p-2

InChI key

OTYPIDNRISCWQY-UHFFFAOYSA-L

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of the 12 Principles of Green Chemistry. This catalyst combines proven scalability with exceptional economic viability for commercial processes. Its reliability and extended lifetime minimize downtime and enable large-scale synthesis with consistent quality. Click here for more information.
Dichlorobis(tri-o-tolylphosphine)palladium(II) is a useful catalyst for C-C and C-N coupling reactions.

Application

Dichlorobis(tri-o-tolylphosphine)palladium(II) has been employed as catalyst for the following studies:
  • Reaction of tributyltin enolates, prepared in situ from tributyltin methoxide and enol acetates, with aryl bromides.
  • Coupling reaction of aryl bromides with vinylic acetates.
  • Negishi-Reformatsky coupling reaction of aryl bromides with ethyl 2-(tributylstannyl)acetates.
  • Synthesis of (E)-methyl 3-(7-indolyl)-2-methacrylate, via Heck reaction.
  • Synthesis of imidazopyrimidine derivatives.
Application Guide for Palladium Catalyzed Cross-Coupling Reactions

Catalyst for C-C and C-N coupling reaction.

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

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