459992
Beryllium
foil, thickness 0.5 mm, 99% trace metals basis
Synonym(s):
Glucinium
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About This Item
Empirical Formula (Hill Notation):
Be
CAS Number:
Molecular Weight:
9.01
UNSPSC Code:
12352300
PubChem Substance ID:
EC Number:
231-150-7
MDL number:
assay
99% trace metals basis
form
foil
autoignition temp.
1198 °F
reaction suitability
reagent type: catalyst
core: beryllium
resistivity
4.46 μΩ-cm, 20°C
thickness
0.5 mm
bp
2970 °C (lit.)
mp
1278 °C (lit.)
density
1.85 g/mL at 25 °C (lit.)
SMILES string
[Be]
InChI
1S/Be
InChI key
ATBAMAFKBVZNFJ-UHFFFAOYSA-N
Application
Reagent for synthesis of:
Reagent for:
- Beryllium phthalocyanine and its derivatives
- Catalyst with cerium oxide for oxidative coupling of methane
- Organoberyllium compounds
Reagent for:
- Metal mediated dechlorination
- Stereoselective Horner-Wadsworth-Emmons reactions
Preparation Note
525 mg = 25 × 25 mm
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signalword
Danger
Hazard Classifications
Acute Tox. 3 Oral - Carc. 1B - Eye Irrit. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT RE 1
Storage Class
6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Regulatory Information
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I. I. Lapkin and S. V. Sinani,
Zh. Obshch. Khim., 57, 372-375 (1987)
David D Díaz et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 12(9), 2593-2606 (2006-01-10)
A highly regio- and stereoselective intramolecular [1,5]-hydrogen-transfer process is described. Treatment of gamma-benzyl-protected Co2(CO)6-alpha,gamma-acetylenic diols with BF3 x OEt2 provides bis-homopropargylic alcohols. The reaction occurs within seconds, tolerates a wide range of functionalities, and provides good yields. When the ether
K. Otsuka, et al.,
Chemistry Letters (Jpn), 9, 1835-1838 (1987)