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Merck
CN

459992

Sigma-Aldrich

Beryllium

foil, thickness 0.5 mm, 99% trace metals basis

Synonym(s):

Glucinium

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About This Item

Empirical Formula (Hill Notation):
Be
CAS Number:
7440-41-7
Molecular Weight:
9.01
EC Number:
231-150-7
MDL number:
MFCD00134032
UNSPSC Code:
12352300
PubChem Substance ID:
24869632

Key Documents

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Assay

99% trace metals basis

form

foil

autoignition temp.

1198 °F

reaction suitability

reagent type: catalyst
core: beryllium

resistivity

4.46 μΩ-cm, 20°C

thickness

0.5 mm

bp

2970 °C (lit.)

mp

1278 °C (lit.)

density

1.85 g/mL at 25 °C (lit.)

SMILES string

[Be]

InChI

1S/Be

InChI key

ATBAMAFKBVZNFJ-UHFFFAOYSA-N

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Application

Reagent for synthesis of:
  • Beryllium phthalocyanine and its derivatives
  • Catalyst with cerium oxide for oxidative coupling of methane
  • Organoberyllium compounds

Reagent for:
  • Metal mediated dechlorination
  • Stereoselective Horner-Wadsworth-Emmons reactions

Preparation Note

525 mg = 25 × 25 mm

Pictograms

Skull and crossbonesHealth hazard
GHS06,GHS08

Signal Word

Danger

Hazard Classifications

Acute Tox. 3 Oral - Carc. 1B - Eye Irrit. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT RE 1

Storage Class Code

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

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Certificates of Analysis (COA)

Lot/Batch Number
02216AJ
03808PH
07119MO
11728HQ
09719JO

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David D Díaz et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 12(9), 2593-2606 (2006-01-10)
A highly regio- and stereoselective intramolecular [1,5]-hydrogen-transfer process is described. Treatment of gamma-benzyl-protected Co2(CO)6-alpha,gamma-acetylenic diols with BF3 x OEt2 provides bis-homopropargylic alcohols. The reaction occurs within seconds, tolerates a wide range of functionalities, and provides good yields. When the ether
I. I. Lapkin and S. V. Sinani,
Zh. Obshch. Khim., 57, 372-375 (1987)
K. Otsuka, et al.,
Chemistry Letters (Jpn), 9, 1835-1838 (1987)
A Hermanne et al.
Applied radiation and isotopes : including data, instrumentation and methods for use in agriculture, industry and medicine, 70(12), 2763-2772 (2012-10-10)
New experimental data for production of (7)Be and (22,24)Na in deuteron irradiation of (nat)Mg and Al up to 50 MeV are presented. The induced activity, measured with HPGe spectroscopy, allows us to determine excitation functions of (nat)Mg(d,x) and (27)Al(d,x) reactions
V. K. Tandon and R. B. Chhor,
Letters in Organic Chemistry, 1, 40-42 (2004)
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