460990
Sodium trans-hyponitrite hydrate
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About This Item
Linear Formula:
Na2N2O2 · xH2O
CAS Number:
Molecular Weight:
105.99 (anhydrous basis)
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352302
MDL number:
Form:
solid
InChI
1S/H2N2O2.2Na.H2O/c3-1-2-4;;;/h(H,1,4)(H,2,3);;;1H2/q;2*+1;/p-2
SMILES string
[Na+].[Na+].[H]O[H].[O-]\N=N\[O-]
InChI key
MNTPJDLNJKAOKU-UHFFFAOYSA-L
form
solid
storage temp.
2-8°C
Quality Level
Related Categories
Application
Precursor to tert-butyl hyponitrite which was employed in the low-temperature thermal generation of tert-butoxy radicals.
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
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An umpolung approach to cis-hyponitrite complexes.
Navamoney Arulsamy et al.
Angewandte Chemie (International ed. in English), 41(13), 2371-2373 (2002-08-31)
Hyun Joo et al.
The journal of physical chemistry. A, 109(7), 1420-1429 (2006-07-13)
In the reaction of F2PBr, F2P(O)Br, (C6F5)2PBr, (CH3)2P(S)Br, and (CH3)2P(O)Cl with silver hyponitrite (AgON=NOAg), nitrous oxide (N2O) and mu-oxo phosphorus species were obtained in all cases rather than the plausible hyponitrite alternative. Theoretical calculations of the geometries and expected decomposition
T C Hollocher et al.
The Journal of biological chemistry, 255(11), 5027-5030 (1980-06-10)
13N- and 15N-labeling experiments were carried out with Paracoccus denitrificans, grown anaerobically on nitrate, to determine whether hyponitrite might be an obligatory intermediate in denitrification and a precursor of nitrous oxide. From experiments designed to trap [13N]- or [15N,15N]hyponitrite by
Nan Xu et al.
Journal of the American Chemical Society, 131(7), 2460-2461 (2009-02-05)
The coupling of two nitric oxide (NO) molecules in heme active sites is an important contributor to the conversion of NO to nitrous oxide (N(2)O) by heme-containing enzymes. Several formulations for the presumed heme-Fe{N(2)O(2)}(n-) intermediates have been proposed previously, however
Gregory A Poskrebyshev et al.
Journal of the American Chemical Society, 126(3), 891-899 (2004-01-22)
All major properties of the aqueous hyponitrite radicals (ONNO- and ONNOH), the adducts of nitric oxide (NO) and nitroxyl (3NO- and 1HNO), are revised. In this work, the radicals are produced by oxidation of various hyponitrite species in the 2-14
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