461075
1-(Trimethylsilyl)-2-pyrrolidinone
96%
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About This Item
Empirical Formula (Hill Notation):
C7H15NOSi
CAS Number:
Molecular Weight:
157.29
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
238-461-7
MDL number:
InChI key
LUBVCBITQHEVCJ-UHFFFAOYSA-N
InChI
1S/C7H15NOSi/c1-10(2,3)8-6-4-5-7(8)9/h4-6H2,1-3H3
SMILES string
C[Si](C)(C)N1CCCC1=O
assay
96%
refractive index
n20/D 1.46 (lit.)
bp
90 °C/20 mmHg (lit.)
density
0.983 g/mL at 25 °C (lit.)
General description
1-(Trimethylsilyl)-2-pyrrolidinone has been prepared by refluxing a mixture of 2-pyrrolidinone, triethylamine and trimethylchlorosilane in benzene. It undergoes sulfenylation with phenyl disulfide to form the corresponding bissulfide as the major product.
Application
1-(Trimethylsilyl)-2-pyrrolidinone may be used for the preparation of 1-(diphenylphosphonio)pyrrolidin-2-one and 1-(1-adamantylcarbonyl)-2-pyrrolidinone.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
3 - Flammable liquids
wgk
WGK 3
flash_point_f
127.4 °F - closed cup
flash_point_c
53 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Regulatory Information
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Synthesis, conformational characteristics and anti-influenza virus A activity of some 2-adamantylsubstituted azacycles.
Setaki D, et al.
Bioorganic Chemistry, 34(5), 248-273 (2006)
Synthesis and antiviral activity evaluation of some new aminoadamantane derivatives. 2.
Kolocouris N, et al.
Journal of Medicinal Chemistry, 39(17), 3307-3318 (1996)
Sulfenylation and sulfinylation of lactams and imino ethers.
Zoretic PA, et al.
The Journal of Organic Chemistry, 43(7), 1379-1382 (1978)
Efficient method for the preparation of carboxylic acid alkyl esters or alkyl phenyl ethers by a new-type of oxidation-reduction condensation using 2, 6-dimethyl-1, 4-benzoquinone and alkoxydiphenylphosphines.
Shintou T, et al.
Bulletin of the Chemical Society of Japan, 76(8), 1645-1667 (2003)
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