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463736

Sodium hexanitrocobaltate(III)

99.999% trace metals basis

Synonym(s):

Sodium cobaltnitrite, Sodium hexanitritocobaltate(III)

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About This Item

Linear Formula:
Na3Co(NO2)6
CAS Number:
13600-98-1
Molecular Weight:
403.94
UNSPSC Code:
12352302
PubChem Substance ID:
24870090
EC Number:
237-077-7
MDL number:
MFCD00003512
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assay

99.999% trace metals basis

form

solid

mp

220 °C (dec.) (lit.)

SMILES string

[Na+].[Na+].[Na+].[O-][N+](=O)[Co-3]([N+]([O-])=O)([N+]([O-])=O)([N+]([O-])=O)([N+]([O-])=O)[N+]([O-])=O

InChI

1S/Co.6NO2.3Na/c;6*2-1-3;;;/q-3;;;;;;;3*+1

InChI key

IMBXIBFCGMYSME-UHFFFAOYSA-N

Application

Nitrosation reagent for the conversion of aromatic amines to 1,3-diaryltriazenes with excellent yield.

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Danger

Hazard Classifications

Carc. 2 - Eye Irrit. 2 - Ox. Sol. 2 - Resp. Sens. 1 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

target_organs

Respiratory system

Storage Class

5.1B - Oxidizing hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

Regulatory Information

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Certificates of Analysis (COA)

Lot/Batch Number
MKBF6881V
MKBF7406V
MKBB7562
03222KH
03901MB

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Bogdan Stefane et al.
The Journal of organic chemistry, 62(21), 7165-7169 (2001-10-24)
Na(3)Co(NO(2))(6) has been investigated as a new reagent for the nitrosation of various substrates containing an amino functionality. Reactions took place in an aqueous solution of the reagent. The pH of the reaction mixture remained in the range 4.3-5. Thus
[Hygienic standard basis for potassium hexanitrocobaltate in the water of reservoirs].
A A Korolev
Gigiena i sanitariia, (10)(10), 72-73 (1980-10-01)
D B Green et al.
Stain technology, 65(1), 15-24 (1990-01-01)
The effect was examined of the chemical decomposition of the potassium stain sodium hexanitrocobaltate (III) (SHC), on its ability to produce stain granules of consistent size that could be used to estimate the K+ contents of stomatal guard cells. Stomata
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