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Merck
CN

464236

Zirconium(IV) hydrogenphosphate

Synonym(s):

α-Zirconium phosphate, γ-Zirconium phosphate, Zirconium bis(hydrogen phosphate), Zirconium bis(monohydrogen orthophosphate), Zirconium hydrogen orthophosphate

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About This Item

Linear Formula:
Zr(HPO4)2
CAS Number:
Molecular Weight:
283.18
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
237-401-7
MDL number:
Form:
powder
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InChI key

QOKYJGZIKILTCY-UHFFFAOYSA-J

InChI

1S/2H3O4P.Zr/c2*1-5(2,3)4;/h2*(H3,1,2,3,4);/q;;+4/p-4

SMILES string

[Zr+4].OP([O-])([O-])=O.OP([O-])([O-])=O

form

powder

reaction suitability

core: zirconium
reagent type: catalyst

density

3.3 g/mL at 25 °C (lit.)

Quality Level

Application

Employed in the preparation of layered organic-inorganic, hybrid, conducting materials.

pictograms

Exclamation mark

signalword

Warning

hcodes

Hazard Classifications

Skin Sens. 1

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)


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Carissa M Vetromile et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 78(2), 648-652 (2011-01-11)
In this report the photo-physical properties of 9-amino acridine (9AA) associated with αZr-phosphate particles (αZrP) is examined. In ethanol solution 9AA exhibits absorption maxima at 425 nm, 402 nm and 383 nm as well as emission bands centered at 455
Backov, R. et al.
Chemistry of Materials, 9, 1812-1812 (1997)
Ajith Pattammattel et al.
Langmuir : the ACS journal of surfaces and colloids, 29(9), 2971-2981 (2013-02-05)
Previously, an ion-coupled protein binding (ICPB) model was proposed to explain the thermodynamics of protein binding to negatively charged α-Zr(IV) phosphate (α-ZrP). This model is tested here using glucose oxidase (GO) and met-hemoglobin (Hb) and several cations (Zr(IV), Cr(III), Au(III)
Roxane M Fabre et al.
Langmuir : the ACS journal of surfaces and colloids, 28(5), 2835-2841 (2012-01-11)
Skeletonized zirconium phosphonate surfaces are used to support planar lipid bilayers and are shown to be viable substrates for studying transmembrane proteins. The skeletonized surfaces provide space between the bilayer and the solid support to enable protein insertion and avoid
Angel A Martí et al.
Inorganic chemistry, 49(16), 7298-7303 (2010-08-10)
We studied the structures, luminescence, and self-quenching properties of tris(2,2'-bipyridyl)ruthenium(II) (Ru(bpy)(3)(2+)) two-dimensional arrangements within the layers of zirconium phosphate (ZrP). The intercalation of Ru(bpy)(3)(2+) was accomplished using a hydrated form of zirconium phosphate ZrP. Varying the Ru(bpy)(3)(2+)/ZrP intercalation ratio, different

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