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467030

1-Cyclohexene-1-carboxaldehyde

Name: 1-Cyclohexene-1-carboxaldehyde
Brand: ALDRICH

97%

Synonym(s):

Δ1-Tetrahydrobenzaldehyde, 1-Cyclohexenecarboxaldehyde, 1-Cyclohexenylaldehyde, 1-Formyl-1-cyclohexene, 1-Formylcyclohexene

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About This Item

Linear Formula:

C₆H₉CHO

CAS Number:

1192-88-7

Molecular Weight:

110.15

NACRES:

NA.22

PubChem Substance ID:

24870379

UNSPSC Code:

12352100

MDL number:

MFCD00674109

Assay:

97%

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Properties

Quality Level

100

assay

97%

bp

61 °C/10 mmHg (lit.)

density

0.966 g/mL at 25 °C (lit.)

functional group

aldehyde

SMILES string

O=CC1=CCCCC1

InChI

1S/C7H10O/c8-6-7-4-2-1-3-5-7/h4,6H,1-3,5H2

InChI key

OANSOJSBHVENEI-UHFFFAOYSA-N

Description

General description

1-Cyclohexene-1-carboxaldehyde is an α,β-unsaturated aldehyde. It participates in the synthesis of benzopyrans.

Application

1-Cyclohexene-1-carboxaldehyde may be used in the synthesis of azomethine imines.

Storage Class

10 - Combustible liquids

wgk

WGK 3

flash_point_f

149.0 °F - closed cup

flash_point_c

65 °C - closed cup

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1,3-Dipolar cycloaddition of arynes with azomethine imines: synthesis of 1,2-dihydropyrazolo[1,2-a]indazol-3(9H)-ones.

Feng Shi et al.

Tetrahedron letters, 50(28), 4067-4070 (2010-02-18)

A [3+2] 1,3-dipolar cycloaddition reaction of arynes with stable azomethine imines has been developed. The reaction rapidly assembles tricyclic pyrazoloindazolone derivatives in moderate yields under mild reaction conditions.

Environmentally benign, one-pot synthesis of pyrans by domino Knoevenagel/6p-electrocyclization in water and application to natural products.

Jung EJ, et al.

Green Chemistry, 12(11), 2003-2011 (2010)

Efficient and general method for the synthesis of benzopyrans by ethylenediamine diacetate-catalyzed reactions of resorcinols with α, β-unsaturated aldehydes. One step synthesis of biologically active (?)-confluentin and (?)-daurichromenic acid.

Lee YR, et al.

Tetrahedron Letters, 46(44), 7539-7543 (2005)

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Global Trade Item Number

SKU	GTIN
M8449-10UG	04061833247495
467030-1G	04061837500077
467030-5G	04061837500084