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Merck
CN

467030

1-Cyclohexene-1-carboxaldehyde

97%

Synonym(s):

Δ1-Tetrahydrobenzaldehyde, 1-Cyclohexenecarboxaldehyde, 1-Cyclohexenylaldehyde, 1-Formyl-1-cyclohexene, 1-Formylcyclohexene

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About This Item

Linear Formula:
C6H9CHO
CAS Number:
Molecular Weight:
110.15
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
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Product Name

1-Cyclohexene-1-carboxaldehyde, 97%

InChI

1S/C7H10O/c8-6-7-4-2-1-3-5-7/h4,6H,1-3,5H2

SMILES string

O=CC1=CCCCC1

InChI key

OANSOJSBHVENEI-UHFFFAOYSA-N

assay

97%

bp

61 °C/10 mmHg (lit.)

density

0.966 g/mL at 25 °C (lit.)

functional group

aldehyde

Quality Level

Application

1-Cyclohexene-1-carboxaldehyde may be used in the synthesis of azomethine imines.

General description

1-Cyclohexene-1-carboxaldehyde is an α,β-unsaturated aldehyde. It participates in the synthesis of benzopyrans.

Storage Class

10 - Combustible liquids

wgk

WGK 3

flash_point_f

149.0 °F - closed cup

flash_point_c

65 °C - closed cup


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Environmentally benign, one-pot synthesis of pyrans by domino Knoevenagel/6p-electrocyclization in water and application to natural products.
Jung EJ, et al.
Green Chemistry, 12(11), 2003-2011 (2010)
Feng Shi et al.
Tetrahedron letters, 50(28), 4067-4070 (2010-02-18)
A [3+2] 1,3-dipolar cycloaddition reaction of arynes with stable azomethine imines has been developed. The reaction rapidly assembles tricyclic pyrazoloindazolone derivatives in moderate yields under mild reaction conditions.
Yi Wang et al.
Plant, cell & environment, 44(2), 559-573 (2020-11-21)
In plants, cellular lipid peroxidation is enhanced under low nitrogen (LN) stress; this increases the lipid-derived reactive carbonyl species (RCS) levels. The cellular toxicity of RCS can be reduced by various RCS-scavenging enzymes. However, the roles of these enzymes in
Efficient and general method for the synthesis of benzopyrans by ethylenediamine diacetate-catalyzed reactions of resorcinols with α, β-unsaturated aldehydes. One step synthesis of biologically active (?)-confluentin and (?)-daurichromenic acid.
Lee YR, et al.
Tetrahedron Letters, 46(44), 7539-7543 (2005)

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