468207
Iron(III) tris(2,2,6,6-tetramethyl-3,5-heptanedionate)
Synonym(s):
Fe(TMHD)3
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About This Item
Linear Formula:
Fe[(CH3)3CCOCHCOC(CH3)3]
CAS Number:
Molecular Weight:
605.65
UNSPSC Code:
12352300
PubChem Substance ID:
MDL number:
InChI
1S/3C11H20O2.Fe/c3*1-10(2,3)8(12)7-9(13)11(4,5)6;/h3*7,12H,1-6H3;/q;;;+3/p-3/b2*8-7+;8-7-;
SMILES string
CC(C)(C)C(=O)\C=C(\O[Fe](O\C(=C\C(=O)C(C)(C)C)C(C)(C)C)O\C(=C/C(=O)C(C)(C)C)C(C)(C)C)C(C)(C)C
InChI key
NXBJVTQWYMSPSJ-GECNZSFWSA-K
reaction suitability
core: iron
mp
179-185 °C (lit.)
Application
Precursor for the formation of BaFe12O19 thin films on Al2O3 (0001) substrates in preferential orientation with the c-axis perpendicular to the substrate. Precursor for aerosol-assisted CVD of mixed-conducting ceramic films of Sr-Co-Fe perovskite phases.
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
Regulatory Information
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Calvin D Pham et al.
ACS applied materials & interfaces, 9(42), 36980-36988 (2017-09-20)
A radical-enhanced atomic layer deposition (RE-ALD) process was developed for growing ferrimagnetic CoFe
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