470449
Tetrakis[1-[[4-alkyl(C11-C13)phenyl]sulfonyl]-(2S)-pyrrolidinecarboxylate]dirhodium(II)
Synonym(s):
Rh2(S-DOSP)4
form
solid
optical activity
[α]20/D −165°, c = 1 in chloroform
reaction suitability
reaction type: Asymmetric synthesis
reaction type: C-H Activation
reagent type: catalyst
reaction type: Cyclopropanations
mp
195-200 °C (lit.)
storage temp.
2-8°C
Application
Catalyst for asymmetric cyclopropanations.
Catalyst involved in:
- Stereoselective reactions of aryl- and styryldiazoacetates
- Enantioselective C-H carbene insertions
- Asymmetric cyclopropenation of aryl alkynes
- Intermolecular C-H olefination
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
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Davies, H.M.L. Hutcheson, D.K.
Tetrahedron Letters, 34, 7243-7243 (1993)
Davies, H.M.L. et al.
Tetrahedron Letters, 37, 4133-4133 (1996)
Davies, H.M.L. et al.
Tetrahedron Letters, 38, 1741-1741 (1997)
Davies, H.M.L. et al.
Journal of the American Chemical Society, 118, 6897-6897 (1996)
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