472794
3,4-Di-O-acetyl-6-O-(tert-butyldiphenylsilyl)-D-glucal
97%
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About This Item
Empirical Formula (Hill Notation):
C26H32O6Si
CAS Number:
Molecular Weight:
468.61
UNSPSC Code:
12352200
PubChem Substance ID:
MDL number:
assay
97%
InChI
1S/C26H34O8Si/c1-18(28)33-24(22(30)16-27)25(34-19(2)29)23(31)17-32-35(26(3,4)5,20-12-8-6-9-13-20)21-14-10-7-11-15-21/h6-16,22-25,30-31H,17H2,1-5H3/t22-,23+,24+,25+/m0/s1
SMILES string
CC(=O)O[C@@H]1C=CO[C@H](CO[Si](c2ccccc2)(c3ccccc3)C(C)(C)C)[C@H]1OC(C)=O
InChI key
PYGIMOKQSQTVMY-ZYQDXHPFSA-N
optical activity
[α]20/D +9°, c = 1.1 in chloroform
refractive index
n20/D 1.456 (lit.)
Application
Important building block for both solution- and solid-phase synthesis of oligosaccharides.
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Seeberger, P.H., et al.
Aldrichimica Acta, 30, 75-75 (1997)
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