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Merck
CN

473804

2-Bromophenylboronic acid

≥95.0%

Sustainability features

Synonym(s):

o-Bromophenylboronic acid

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About This Item

Linear Formula:
BrC6H4B(OH)2
CAS Number:
Molecular Weight:
200.83
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352103
MDL number:
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Quality Segment

assay

≥95.0%

sustainability

Sustainability features

mp

113 °C (lit.)

functional group

bromo

SMILES string

OB(O)c1ccccc1Br

InChI

1S/C6H6BBrO2/c8-6-4-2-1-3-5(6)7(9)10/h1-4,9-10H

InChI key

PLVCYMZAEQRYHJ-UHFFFAOYSA-N

General description

This product aligns with one or more of the 12 Principles of Green Chemistry Find details here.

Application

Catalyzes the formation of amide bonds from amines and carboxylic acids.
Used to promote greener amidations of carboxylic acids and amines in catalytic amounts. This technology avoids the requirement of preactivation of the carboxylic acid or use of coupling reagents.

Direct Amidation of Carboxylic Acids Catalyzed by ortho-Iodo Arylboronic Acids: Catalyst Optimization, Scope, and Preliminary Mechanistic Study Supporting a Peculiar Halogen Acceleration Effect

Other Notes

Contains varying amounts of anhydride


Pictograms

Exclamation mark

Signal Word

Warning

Hazard Codes

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class

11 - Combustible Solids

WGK

WGK 3



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