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Merck
CN

473804

2-Bromophenylboronic acid

greener alternative

≥95.0%

Synonym(s):

o-Bromophenylboronic acid

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About This Item

Linear Formula:
BrC6H4B(OH)2
CAS Number:
244205-40-1
Molecular Weight:
200.83
NACRES:
NA.22
PubChem Substance ID:
24870934
UNSPSC Code:
12352103
MDL number:
MFCD01114672

Key Documents

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Product Name

2-Bromophenylboronic acid, ≥95.0%

InChI

1S/C6H6BBrO2/c8-6-4-2-1-3-5(6)7(9)10/h1-4,9-10H

SMILES string

OB(O)c1ccccc1Br

InChI key

PLVCYMZAEQRYHJ-UHFFFAOYSA-N

assay

≥95.0%

greener alternative product characteristics

Catalysis
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sustainability

Greener Alternative Product

mp

113 °C (lit.)

functional group

bromo

greener alternative category

Aligned,

Quality Level

200

Related Categories

Application

Catalyzes the formation of amide bonds from amines and carboxylic acids.
Used to promote greener amidations of carboxylic acids and amines in catalytic amounts. This technology avoids the requirement of preactivation of the carboxylic acid or use of coupling reagents.

Direct Amidation of Carboxylic Acids Catalyzed by ortho-Iodo Arylboronic Acids: Catalyst Optimization, Scope, and Preliminary Mechanistic Study Supporting a Peculiar Halogen Acceleration Effect

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalysis. Find details here.

Other Notes

Contains varying amounts of anhydride

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk

WGK 3

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Certificates of Analysis (COA)

Lot/Batch Number
WXBF5648V
WXBF2084V
WXBD9735V
WXBD6131V
WXBD1789V

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Yae In Cho et al.
Inorganic chemistry, 58(19), 12689-12699 (2019-09-10)
We report syntheses and H2 activation involving model complexes of mono-iron hydrogenase (Hmd) derived from acyl-containing pincer ligand precursors bearing thioether (CNS

Articles

Greener Methods: Catalytic Amide Bond Formation

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