474592
(R,R)-(-)-N,N′-双(3,5-二-叔丁基亚水杨基)-1,2-环己二胺钴(II)
别名:
(R,R)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminatocobalt(II), (R,R)-Co(salen), (R,R)-Jacobsen HKR catalyst
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关于此项目
线性分子式:
[[[(CH3)3C]2C6H2-2-(O-)CH=N]2C6H10]Co
化学文摘社编号:
分子量:
603.74
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352001
MDL number:
mp
>350 °C (lit.)
Quality Segment
SMILES string
CC(C)(C)c1cc2C=[N@H]3[C@@H]4CCCC[C@H]4[N@@H]5=Cc6cc(cc(c6O[Co]35Oc2c(c1)C(C)(C)C)C(C)(C)C)C(C)(C)C
InChI
1S/C36H54N2O2.Co/c1-33(2,3)25-17-23(31(39)27(19-25)35(7,8)9)21-37-29-15-13-14-16-30(29)38-22-24-18-26(34(4,5)6)20-28(32(24)40)36(10,11)12;/h17-22,29-30,39-40H,13-16H2,1-12H3;/q;+2/p-2/b37-21+,38-22+;/t29-,30-;/m1./s1
InChI key
ZFWPDJKMASHRPT-CITKKJEGSA-L
Application
用于末端环氧化物的水解动力学拆分和内消旋环氧化物不对称开环的催化剂。
signalword
Danger
hcodes
Hazard Classifications
Aquatic Chronic 3 - Skin Sens. 1A - STOT RE 1
存储类别
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves