474800
tert-Butyl N,N-diallylcarbamate
98%
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About This Item
Linear Formula:
(H2C=CHCH2)2NCO2C(CH3)3
CAS Number:
Molecular Weight:
197.27
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
Assay:
98%
InChI
1S/C11H19NO2/c1-6-8-12(9-7-2)10(13)14-11(3,4)5/h6-7H,1-2,8-9H2,3-5H3
SMILES string
CC(C)(C)OC(=O)N(CC=C)CC=C
InChI key
RRIPHUBKNVVTBM-UHFFFAOYSA-N
assay
98%
refractive index
n20/D 1.442 (lit.)
bp
75 °C/1.5 mmHg (lit.)
density
0.914 g/mL at 25 °C (lit.)
General description
tert-Butyl N,N-diallylcarbamate is a protected amine. Ring-closing metathesis (RCM) reactions of tert-butyl N,N-diallylcarbamate in the presence of Hoveyda-Grubbs type catalyst supported on mesoporous molecular sieves have been reported.
Application
tert-Butyl N,N-diallylcarbamate may be used in the synthesis of heterocyclic compounds.
Storage Class
10 - Combustible liquids
wgk
WGK 3
flash_point_f
177.8 °F - closed cup
flash_point_c
81 °C - closed cup
Regulatory Information
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Copper-Catalyzed Synthesis of 1, 2-Disubstituted Cyclopentanes from 1, 6-Dienes by Ring-Closing Kharasch Addition of Carbon Tetrachloride.
Mu?oz-Molina JM, et al.
Advanced Synthesis & Catalysis, 350(14-15), 2365-2372 (2008)
Hynek Balcar et al.
Beilstein journal of organic chemistry, 7, 22-28 (2011-02-03)
A commercially available Hoveyda-Grubbs type catalyst (RC303 Zhannan Pharma) was immobilized on mesoporous molecular sieves MCM-41 and on SBA-15 by direct interaction with the sieve wall surface. The immobilized catalysts exhibited high activity and nearly 100% selectivity in several types
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