477079
2,3-Dihydro-1,4-dithiino[2,3-c]furan-5,7-dione
97%
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About This Item
Empirical Formula (Hill Notation):
C6H4O3S2
CAS Number:
Molecular Weight:
188.22
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
Assay
97%
mp
112-115 °C (lit.)
SMILES string
O=C1OC(=O)C2=C1SCCS2
InChI
1S/C6H4O3S2/c7-5-3-4(6(8)9-5)11-2-1-10-3/h1-2H2
InChI key
MXSSHXZXAAXCOW-UHFFFAOYSA-N
General description
2,3-Dihydro-1,4-dithiino[2,3-c]furan-5,7-dione is an anhydride of dicarboxylic acid.
Application
2,3-Dihydro-1,4-dithiino[2,3-c]furan-5,7-dione (5,6-dihydro-1,4-dithiin-2,3-dicarboxylic anhydride, dhca, 3,6-Dithia-3,4,5,6-tetrahydrophthalic anhydride) may be used in the synthesis of the following:
- photoluminescent three-dimensional (3-D) AgI coordination polymer
- 5,6-dihydro-1,4- dithiin-2,3-dicarboxylate
- CuII and MnII coordination complexes with 5,6-dihydro-1,4-dithiin-2,3-dicarboxylate as a primary building block
- 2-heteroaryl-4,7-dithia-4,5,6,7-tetrahydro-1,3-indandiones
- 3-arylmethylene-4,7-dithia-4,5,6,7-tetrahydrophthalides
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Regulatory Information
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Phthalides and 1, 3-indandiones. LII. Reactions of 3, 6-dithia-3, 4, 5, 6-tetrahydrophthalic anhydride with methyl derivatives of nitrogen-containing heterocycles.
Krasnec L and Hrnciar P.
Chemical Papers, 28(1), 100-105 (1974)
In situ syntheses, crystal structures and magnetic properties of CuII and MnII coordination assemblies based on a novel heteroalicyclic dicarboxylate tecton and N-donor co-ligands.
Liu CS, et al.
CrystEngComm, 14(1), 160-168 (2012)
A 3-D silver (I) polymer with 5, 6-dihydro-1, 4-dithiin-2, 3-dicarboxylate ligand, showing an unusual 6-connected (4 12. 6 3) 2 (4 9. 6 6) topology.
Hu M, et al.
Inorganic Chemistry Communications, 13(12), 1548-1551 (2010)
Phthalides and 1,3-indandiones. XLIX. Preparation of 3-arylmethylene-4,7-dithia-4,5-6,7-tetrahydrophthalides and 2-aryl-4,7-dithia-4,5,6,7-tetrahydro-1,3-indandiones.
Hrnciar P.
Chemical Papers, 27(3) , 372-380 (1973)
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