477761
N,N-Diallyl-2,2,2-trifluoroacetamide
98%
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About This Item
Linear Formula:
CF3CON(CH2CH=CH2)2
CAS Number:
Molecular Weight:
193.17
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
Assay
98%
refractive index
n20/D 1.413 (lit.)
bp
67-68.5 °C/13 mmHg (lit.)
density
1.13 g/mL at 25 °C (lit.)
functional group
amide
fluoro
SMILES string
FC(F)(F)C(=O)N(CC=C)CC=C
InChI
1S/C8H10F3NO/c1-3-5-12(6-4-2)7(13)8(9,10)11/h3-4H,1-2,5-6H2
InChI key
YLFAOCVUPKJNHP-UHFFFAOYSA-N
General description
N,N-Diallyl-2,2,2-trifluoroacetamide (DAF) is an organic building block used in chemical synthesis. The capability of silica immobilized Hoveyda-Grubbs type catalysts to facilitate the ring-closing metathesis of (-)-β-citronellene and DAF has been investigated. Its density and refractive index at 25°C is 1.1300g/cm3 and 1.4130 respectively.
Application
N,N-Diallyl-2,2,2-trifluoroacetamide may be used as a substrate for ring-closing metathesis (RCM) reaction.
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
10 - Combustible liquids
WGK
WGK 3
Flash Point(F)
147.2 °F - closed cup
Flash Point(C)
64 °C - closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Ru complexes of Hoveyda-Grubbs type immobilized on lamellar zeolites: activity in olefin metathesis reactions.
Balcar H, et al.
Beilstein Journal of Organic Chemistry, 11(1), 2087-2096 (2015)
Yaws CL.
The Yaws Handbook of Physical Properties for Hydrocarbons and Chemicals, 195-195 (2015)
Joseph B Binder et al.
Advanced synthesis & catalysis, 349(3), 395-404 (2007-02-02)
Tuning the electronic and steric environment of olefin metathesis catalysts with specialized ligands can adapt them to broader applications, including metathesis in aqueous solvents. Bidentate salicylaldimine ligands are known to stabilize ruthenium alkylidene complexes, as well as allow ring-closing metathesis
Hynek Balcar et al.
Beilstein journal of organic chemistry, 11, 2087-2096 (2015-12-15)
Hoveyda-Grubbs type catalysts with cationic tags on NHC ligands were linker-free immobilized on the surface of lamellar zeolitic supports (MCM-22, MCM-56, MCM-36) and on mesoporous molecular sieves SBA-15. The activity of prepared hybrid catalysts was tested in olefin metathesis reactions:
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