479438
Lithium tetramethylcyclopentadienide
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About This Item
Linear Formula:
LiC5H(CH3)4
CAS Number:
Molecular Weight:
128.14
MDL number:
UNSPSC Code:
12352300
PubChem Substance ID:
NACRES:
NA.22
reaction suitability
reagent type: ligand
mp
>350 °C (lit.)
SMILES string
[Li].C[C]1[CH][C](C)[C](C)[C]1C
InChI
1S/C9H13.Li.H/c1-6-5-7(2)9(4)8(6)3;;/h5H,1-4H3;;
InChI key
PTQWRLJKGBNMJV-UHFFFAOYSA-N
Application
Reactant for synthesis of:
Reactant with SiH-functionalized cyclopentadienes
Reactant in the reduction of beta-diketiminato-titanium(III) complexes
- Cyclopentadienylphosphanes
- Ansa-cyclopentadienyl-phenoxy titanium(IV) complexes
- Titanium and zirconium complexes
- Hafnocene catalysts
Reactant with SiH-functionalized cyclopentadienes
Reactant in the reduction of beta-diketiminato-titanium(III) complexes
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Pyr. Sol. 1
Storage Class Code
4.2 - Pyrophoric and self-heating hazardous materials
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Regulatory Information
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