479438
Lithium tetramethylcyclopentadienide
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About This Item
Linear Formula:
LiC5H(CH3)4
CAS Number:
Molecular Weight:
128.14
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352300
MDL number:
InChI
1S/C9H13.Li.H/c1-6-5-7(2)9(4)8(6)3;;/h5H,1-4H3;;
SMILES string
[Li].C[C]1[CH][C](C)[C](C)[C]1C
InChI key
PTQWRLJKGBNMJV-UHFFFAOYSA-N
reaction suitability
reagent type: ligand
mp
>350 °C (lit.)
Application
Reactant for synthesis of:
Reactant with SiH-functionalized cyclopentadienes
Reactant in the reduction of beta-diketiminato-titanium(III) complexes
- Cyclopentadienylphosphanes
- Ansa-cyclopentadienyl-phenoxy titanium(IV) complexes
- Titanium and zirconium complexes
- Hafnocene catalysts
Reactant with SiH-functionalized cyclopentadienes
Reactant in the reduction of beta-diketiminato-titanium(III) complexes
signalword
Danger
hcodes
pcodes
Hazard Classifications
Pyr. Sol. 1
Storage Class
4.2 - Pyrophoric and self-heating hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves
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