480495
1,3-Bis(4-methoxyphenyl)-1,3-propanedione
97%
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About This Item
Linear Formula:
(CH3OC6H4CO)2CH2
CAS Number:
Molecular Weight:
284.31
UNSPSC Code:
12352100
PubChem Substance ID:
EC Number:
242-233-2
MDL number:
Assay:
97%
InChI key
GNMDORSUZRRMFS-UHFFFAOYSA-N
InChI
1S/C17H16O4/c1-20-14-7-3-12(4-8-14)16(18)11-17(19)13-5-9-15(21-2)10-6-13/h3-10H,11H2,1-2H3
SMILES string
COc1ccc(cc1)C(=O)CC(=O)c2ccc(OC)cc2
assay
97%
mp
108-115 °C (lit.)
General description
1,3-Bis(4-methoxyphenyl)-1,3-propanedione is a diketone. It is formed as an intermediate during the synthesis of bisphenols.
Application
1,3-Bis(4-methoxyphenyl)-1,3-propanedione (Hpmdbm) may be used:
- As a reactant in the preparation of 1,3-bis(4-hydroxyphenyl)-1,3-propanedione.
- As a starting material in the synthesis of propylpyrazole triol (PPT).
- As a ligand in the synthesis of [NaFe6(OCH3)12(pmdbm)6]ClO4, an iron(III)-oxo cluster.
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
Regulatory Information
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Single-Ion versus Dipolar Origin of the Magnetic Anisotropy in Iron (III)-Oxo Clusters: A Case Study.
Abbati GL, et al.
Chemistry (Weinheim An Der Bergstrasse, Germany), 7(8), 1796-1807 (2001)
Thermostable and heat resistant aromatic polyethers based on heterocyclic bisphenols.
Rusanov AL and Belomoina NM.
Polymer Science, Series C, 51(1), 87-125 (2009)
β-Diketone reagents for the determination of borate in water.
Lambert JL, et al.
Analytical Chemistry, 50(6), 820-822 (1978)
James J Devery et al.
Synlett : accounts and rapid communications in synthetic organic chemistry, (9)(9), 1490-1494 (2009-01-01)
A convenient approach for the synthesis of tetrasubstituted pyrazoles is described. The method involves the treatment of 1,3-diketones and allyltrimethylsilane with CAN followed by cerium-catalyzed addition of substituted hydrazines to construct pyrazoles in good yields.
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