483532
4-(Dimethylamino)phenylboronic acid
≥95.0%
Synonym(s):
4-(N,N-Dimethylamino)phenylboronic acid, 4-N,N-Dimethylaminobenzeneboronic acid, 4-N,N-Dimethylphenylboronic acid, 4-Dimethylaminobenzeneboronic acid, p-(Dimethylamino)-benzeneboronic acid, [4-(Dimethylamino)phenyl-1-yl]boronic acid, [4-(Dimethylamino)phenyl]boric acid
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About This Item
Linear Formula:
(CH3)2NC6H4B(OH)2
CAS Number:
Molecular Weight:
165.00
UNSPSC Code:
12352103
PubChem Substance ID:
MDL number:
assay
≥95.0%
mp
227 °C (lit.)
SMILES string
CN(C)c1ccc(cc1)B(O)O
InChI
1S/C8H12BNO2/c1-10(2)8-5-3-7(4-6-8)9(11)12/h3-6,11-12H,1-2H3
InChI key
RIIPFHVHLXPMHQ-UHFFFAOYSA-N
Application
Reagent used for
Reagent used in Preparation of
- Suzuki-Miyaura cross-coupling reaction
- Nickel (Ni)-catalyzed Suzuki-Miyaura cross-coupling
- Rhodium (Rh)-catalyzed asymmetric addition reactions
- Palladium (Pd)-catalyzed C-OH bond activation
Reagent used in Preparation of
- Push-pull arylvinyldiazine chromophores
- Helical ortho-phenylene oligomers with terminal push-pull substitution
- Alginate-supported cation-Pd nanoparticle gels as catalysts for the Suzuki-Miyaura cross-coupling reaction
- Organic dyes for dye-sensitized solar cells
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
10 - Combustible liquids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
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Related Content
Dramatic Effect of the Gelling Cation on the Catalytic Performances of Alginate-Supported Palladium Nanoparticles for the Suzuki-Miyaura Reaction
Chtchigrovsky, M.; et al.
Chemistry of Materials, 24, 1505-1510 (2012)
Mamoru Tobisu et al.
Journal of the American Chemical Society, 133(48), 19505-19511 (2011-10-26)
Two protocols for the nickel-catalyzed cross-coupling of aryl fluorides with aryl boronic esters have been developed. The first employs metal fluoride cocatalysts, such as ZrF(4) and TiF(4), which enable Suzuki-Miyaura reactions of aryl fluorides bearing electron-withdrawing (ketones, esters, and CF(3))
Rapid access to 4-substituted-pyrones and 2(5H)-furanones via a palladium-catalyzed C-OH bond activation
Hu, Y.; et al.
Tetrahedron, 67, 7258-7262 (2011)
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 483532-1G | 04061826137000 |