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Merck
CN

483699

Potassium selenocyanate

ReagentPlus®, ≥99%

Synonym(s):

Selenocyanic acid potassium

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About This Item

Linear Formula:
KSeCN
CAS Number:
3425-46-5
Molecular Weight:
144.08
UNSPSC Code:
12352302
NACRES:
NA.23
PubChem Substance ID:
24871910
EC Number:
222-320-1
Beilstein/REAXYS Number:
3912121
MDL number:
MFCD00011366
Assay:
≥99%
Form:
solid

Key Documents

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Product Name

Potassium selenocyanate, ReagentPlus®, ≥99%

InChI key

KYEKHFSRAXRJBR-UHFFFAOYSA-M

InChI

1S/CHNSe.K/c2-1-3;/h3H;/q;+1/p-1

SMILES string

[K][Se]C#N

product line

ReagentPlus®

assay

≥99%

form

solid

reaction suitability

core: potassium

technique(s)

NMR: suitable

mp

147 °C

Quality Level

100

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Application

Increasing interest in solid state NMR of heavy-metal nuclei results in the preparation of several Hg-thiocyanate and selenocyanate compounds as potential models.

Legal Information

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

signalword

Danger

Hazard Classifications

Acute Tox. 2 Oral - Acute Tox. 3 Inhalation - Aquatic Acute 1 - Aquatic Chronic 1 - STOT RE 2

Storage Class

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges

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Certificates of Analysis (COA)

Lot/Batch Number
MKCW4684
MKCS9290
MKCT8065
MKCQ9609
MKCL3044

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Till Blum et al.
Nuclear medicine and biology, 30(4), 361-367 (2003-05-28)
Various aliphatic and aromatic [(75)Se]selenoethers were prepared at the no-carrier-added (n.c.a.) level using a new radiosynthetic pathway, based on the formation of alkyl[(75)Se]selenocyanates as intermediates. Using one-pot model reactions of elemental (75)Se, sodium cyanide and various alkylbromides in ethanol, the
Z H Ye et al.
Chemosphere, 52(9), 1571-1579 (2003-07-18)
Wetland microcosms were used to evaluate the ability of constructed wetlands to remove extremely high concentrations of selenocyanate (SeCN-), arsenic (As), and boron (B) from wastewater generated by a coal gasification plant in Indiana. The wetland microcosms significantly reduced the
Rajmund Mokso et al.
Physical chemistry chemical physics : PCCP, 10(28), 4138-4146 (2008-07-10)
The microwave spectra of propa-1,2-dienyl selenocyanate, H(2)C==C==CHSeC[triple bond]N, and cyclopropyl selenocyanate, C(3)H(5)SeC[triple bond]N, are reported. The spectra of the ground and two vibrationally excited states of the (80)Se isotopologue and the spectrum of the ground state of the (78)Se isotopologue
Xiaoguang Meng et al.
Water research, 36(15), 3867-3873 (2002-10-09)
Batch experiments were conducted to investigate the removal of selenocyanate (SeCN-) from oil refinery wastewater and artificial wastewater with elemental iron [Fe(0)]. The chemical forms of selenium in the reacted solids were determined with X-ray photoelectron spectroscopy (XPS) and a
Mark P de Souza et al.
Plant physiology, 128(2), 625-633 (2002-02-14)
Selenocyanate (SeCN(-)) is a major contaminant in the effluents from some oil refineries, power plants, and in mine drainage water. In this study, we determined the potential of Indian mustard (Brassica juncea) and muskgrass (a macroalga, Chara canescens) for SeCN(-)
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