495794
(S)-Alpine-Boramine™
Synonym(s):
(+)-Isopinocampheylborane TMEDA complex, (+)-N,N′-Bis(monoisopinocampheylborane)-N,N,N′,N′-tetramethylethylenediamine
Sign In to View Organizational & Contract Pricing.
Select a Size
About This Item
Empirical Formula (Hill Notation):
C26H54B2N2
CAS Number:
Molecular Weight:
416.34
UNSPSC Code:
12352000
PubChem Substance ID:
MDL number:
SMILES string
CN(C)CCN(C)C.B[C@@H]1C[C@@H]2C[C@H]([C@H]1C)C2(C)C.B[C@@H]3C[C@@H]4C[C@H]([C@H]3C)C4(C)C
mp
139-141 °C (lit.)
Application
Chiral hydroboration reagent. This amine-borane complex has been used as a polarity-reversal catalyst for the kinetic resolution of racemic esters and ketones.
Legal Information
Alpine-Boramine is a trademark of Sigma-Aldrich Co. LLC
signalword
Danger
hcodes
pcodes
Hazard Classifications
Flam. Sol. 1
Storage Class
4.1B - Flammable solid hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type P3 (EN 143) respirator cartridges
Regulatory Information
新产品
This item has
Choose from one of the most recent versions:
Already Own This Product?
Find documentation for the products that you have recently purchased in the Document Library.
The Journal of Organic Chemistry, 45, 3543-3543 (1980)
Dang, H.-S. et al.
Journal of the Chemical Society. Perkin Transactions 1, 1033-1033 (1994)
Aldrichimica Acta, 20, 30-30 (1987)
Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.
Contact Technical Service