497193
1,4-Bis(hydroxydimethylsilyl)benzene
95%
Sign In to View Organizational & Contract Pricing.
Select a Size
About This Item
Linear Formula:
C6H4[Si(CH3)2OH]2
CAS Number:
Molecular Weight:
226.42
UNSPSC Code:
12352103
PubChem Substance ID:
EC Number:
220-405-8
MDL number:
InChI key
YBNBOGKRCOCJHH-UHFFFAOYSA-N
InChI
1S/C10H18O2Si2/c1-13(2,11)9-5-7-10(8-6-9)14(3,4)12/h5-8,11-12H,1-4H3
SMILES string
C[Si](C)(O)c1ccc(cc1)[Si](C)(C)O
assay
95%
mp
133-136 °C (lit.)
Application
A useful silicon nucleophile for Pd-catalyzed cross-coupling.
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
Regulatory Information
新产品
This item has
Choose from one of the most recent versions:
Already Own This Product?
Find documentation for the products that you have recently purchased in the Document Library.
Scott E Denmark et al.
Journal of the American Chemical Society, 130(48), 16382-16393 (2008-11-13)
The sodium salts of allyldimethylsilanol and 2-butenyldimethylsilanol undergo palladium-catalyzed cross-coupling with a wide variety of aryl bromides to afford allylated and crotylated arenes. The coupling of both silanolates required extensive optimization to deliver the expected products in high yields. The
Denmark, S. E.; Ober, M. H.
Aldrichimica Acta, 36, 75-75 (2003)
Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.
Contact Technical Service