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About This Item
Linear Formula:
H2C=CH(CH2)4ZnBr
CAS Number:
Molecular Weight:
228.45
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352103
MDL number:
InChI
1S/C6H11.BrH.Zn/c1-3-5-6-4-2;;/h3H,1-2,4-6H2;1H;/q;;+1/p-1
SMILES string
Br[Zn]CCCCC=C
InChI key
UQWLQJPHSGOLLO-UHFFFAOYSA-M
concentration
0.5 M in THF
density
0.978 g/mL at 25 °C
storage temp.
2-8°C
Application
5-Hexenylzinc bromide can be used as a starting material in the synthesis of 3,6-bis[(cyclopentyl)methyl]phthalonitrile, a key intermediate in the preparation of octasubstituted phthalocyanines.
Legal Information
Product of Rieke Metals, Inc.
Rieke is a registered trademark of Rieke Metals, Inc.
Rieke is a registered trademark of Rieke Metals, Inc.
signalword
Danger
Hazard Classifications
Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3 - Water-react 2
target_organs
Respiratory system
supp_hazards
Storage Class
4.3 - Hazardous materials which set free flammable gases upon contact with water
wgk
WGK 3
flash_point_f
1.4 °F - closed cup
flash_point_c
-17 °C - closed cup
Regulatory Information
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Phthalocyanines bearing bulky cycloalkylmethyl substituents on non-peripheral sites
Cammidge AN, et al.
Tetrahedron Letters, 50(37), 5254-5256 (2009)
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