498785
2-Methoxybenzylzinc chloride solution
0.5 M in THF
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About This Item
Linear Formula:
CH3OC6H4CH2ZnCl
CAS Number:
Molecular Weight:
222.00
MDL number:
UNSPSC Code:
12352103
PubChem Substance ID:
NACRES:
NA.22
concentration
0.5 M in THF
density
0.937 g/mL at 25 °C
storage temp.
2-8°C
SMILES string
COc1ccccc1C[Zn]Cl
InChI
1S/C8H9O.ClH.Zn/c1-7-5-3-4-6-8(7)9-2;;/h3-6H,1H2,2H3;1H;/q;;+1/p-1
InChI key
NRJJPCZGLGLMEV-UHFFFAOYSA-M
Application
2-Methoxybenzylzinc chloride can be used as:
- An intermediate in the preparation of 2,4-diamino-6-arylmethylquinazolines as possible DHFR inhibitors.
- A model organozinc compound in the Pd-catalyzed synthesis of α-aryl tertiary amides by reacting with carbamoyl chlorides.
- A substrate in the synthesis of forensically significant pyridine and pyrimidine derivatives.
Legal Information
Product of Rieke Metals, Inc.
Rieke is a registered trademark of Rieke Metals, Inc.
Rieke is a registered trademark of Rieke Metals, Inc.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3
Target Organs
Central nervous system, Respiratory system
Supplementary Hazards
Storage Class Code
3 - Flammable liquids
WGK
WGK 3
Flash Point(F)
1.0 °F - closed cup
Flash Point(C)
-17.22 °C - closed cup
Regulatory Information
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Find documentation for the products that you have recently purchased in the Document Library.
Suzuki-Miyaura and Negishi approaches to a series of forensically relevant pyridines and pyrimidines
Blachut D, et al.
Synthesis, 2011(21), 3496-3506 (2011)
A novel method of synthesis of 2, 4-diamino-6-arylmethylquinazolines using palladium (0)-catalyzed organozinc chemistry
Rosowsky A and Chen H
The Journal of Organic Chemistry, 66(22), 7522-7526 (2001)
Preparation of tertiary amides via aryl, heteroaryl, and benzyl organozinc reagents; scope and limitations
Rieke RD and Kim S
Tetrahedron Letters, 53(27), 3478-3481 (2012)
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