498823
2-Methoxyphenylzinc iodide solution
0.5 M in THF
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About This Item
Linear Formula:
CH3OC6H4ZnI
CAS Number:
Molecular Weight:
299.42
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352103
MDL number:
InChI
1S/C7H7O.HI.Zn/c1-8-7-5-3-2-4-6-7;;/h2-5H,1H3;1H;/q;;+1/p-1
SMILES string
COc1ccccc1[Zn]I
InChI key
ODPBGCGZGQFTSZ-UHFFFAOYSA-M
concentration
0.5 M in THF
density
0.996 g/mL at 25 °C
storage temp.
2-8°C
Application
2-Methoxyphenylzinc iodide can be used:
- As a substrate in the synthesis of aryl ketones by reacting with aroyl chlorides.
- As a starting material in the synthesis of sulfones by reacting with DABSO reagent and alkyl halides.
Legal Information
Product of Rieke Metals, Inc.
Rieke is a registered trademark of Rieke Metals, Inc.
Rieke is a registered trademark of Rieke Metals, Inc.
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Danger
hcodes
Hazard Classifications
Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3
target_organs
Central nervous system, Respiratory system
supp_hazards
Storage Class
3 - Flammable liquids
wgk
WGK 3
flash_point_f
1.4 °F - closed cup
flash_point_c
-17 °C - closed cup
Regulatory Information
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Synthesis of sulfones from organozinc reagents, DABSO, and alkyl halides
Rocke BN, et al.
Organic Letters, 16(1), 154-157 (2014)
A versatile protocol for the preparation of highly hindered aryl ketones using organozinc reagents
Cho H and Kim S
Bulletin of the Korean Chemical Society,, 33(9), 3083-3086 (2012)
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