499498
(R)-(+)-3-Methoxy-2-methyl-3-oxopropylzinc bromide solution
0.5 M in THF
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About This Item
Linear Formula:
CH3O2CCH(CH3)CH2ZnBr
CAS Number:
Molecular Weight:
246.42
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352103
MDL number:
InChI
1S/C5H9O2.BrH.Zn/c1-4(2)5(6)7-3;;/h4H,1H2,2-3H3;1H;/q;;+1/p-1/t4-;;/m1../s1
SMILES string
O=C([C@H](C[Zn]Br)C)OC
InChI key
ZYPPBSJLXDMOPY-RZFWHQLPSA-M
concentration
0.5 M in THF
density
0.968 g/mL at 25 °C
storage temp.
2-8°C
Application
(R)-(+)-3-Methoxy-2-methyl-3-oxopropylzinc bromide can be used:
- As an intermediate in one of the key synthetic steps for the preparation of a natural product named (+)-discodermolide.
- As a starting material for the synthesis of (2R,4E)-methyl-2,4-dimethyl-hexanoate, a key intermediate for the preparation of C13-32 fragment of spirangien A.
Legal Information
Product of Rieke Metals, Inc.
Rieke is a registered trademark of Rieke Metals, Inc.
Rieke is a registered trademark of Rieke Metals, Inc.
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Danger
target_organs
Central nervous system, Respiratory system
supp_hazards
Storage Class
4.3 - Hazardous materials which set free flammable gases upon contact with water
wgk
WGK 3
flash_point_f
1.4 °F - closed cup
flash_point_c
-17 °C - closed cup
Hazard Classifications
Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3 - Water-react. 2
Regulatory Information
危险化学品
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Stereoselective synthesis of the C13-32 spiroacetal fragment of spirangien A
Gregg C and Perkins MV
Tetrahedron, 69(33), 6845-6854 (2013)
Formal synthesis of (+)-discodermolide
Francavilla C, et al.
Organic Letters, 5(8), 1233-1236 (2003)
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