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511579

Tetrakis(triphenylphosphine)palladium, polymer-bound

Name: Tetrakis(triphenylphosphine)palladium, polymer-bound
Brand: ALDRICH

100-200 mesh, extent of labeling: 0.4-0.9 mmol/g loading, 2 % cross-linked with divinylbenzene

Synonym(s):

Palladium-tetrakis(triphenylphosphine), polymer-bound

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About This Item

NACRES:

NA.22

PubChem Substance ID:

24873549

UNSPSC Code:

12352200

MDL number:

MFCD00010012

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Properties

form

solid

crosslinking

2 % cross-linked with divinylbenzene

reaction suitability

core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reaction type: solution phase peptide synthesis, reagent type: catalyst

extent of labeling

0.4-0.9 mmol/g loading

particle size

100-200 mesh

storage temp.

2-8°C

SMILES string

[Pd].c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6.c7ccc(cc7)P(c8ccccc8)c9ccccc9.c%10ccc(cc%10)P(c%11ccccc%11)c%12ccccc%12

InChI

1S/4C18H15P.Pd/c4*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;/h4*1-15H;

InChI key

NFHFRUOZVGFOOS-UHFFFAOYSA-N

Description

Application

Polymer-bound catalyst for Suzuki Coupling reactions.^,

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Storage Class

13 - Non Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

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Jang, S-B.

Tetrahedron Letters, 38, 1793-1793 (1997)