514241
2-(tert-Butyldimethylsilyl)-1,3-dithiane
97%
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About This Item
Empirical Formula (Hill Notation):
C10H22S2Si
CAS Number:
Molecular Weight:
234.50
UNSPSC Code:
12352100
PubChem Substance ID:
MDL number:
InChI
1S/C10H22S2Si/c1-10(2,3)13(4,5)9-11-7-6-8-12-9/h9H,6-8H2,1-5H3
SMILES string
CC(C)(C)[Si](C)(C)C1SCCCS1
InChI key
JISLIURJHXAPTN-UHFFFAOYSA-N
assay
97%
refractive index
n20/D 1.531 (lit.)
bp
124 °C/5 mmHg (lit.)
density
1.01 g/mL at 25 °C (lit.)
Packaging
A versatile acyl anion equivalent.
Storage Class
10 - Combustible liquids
wgk
WGK 3
flash_point_f
221.0 °F - closed cup
flash_point_c
105.00 °C - closed cup
ppe
Eyeshields, Gloves
Regulatory Information
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A B Smith et al.
Organic letters, 1(12), 2001-2004 (2000-06-03)
[formula: see text] An efficient synthesis of trisacetonide (+)-11, the Schreiber C(16-28) subtarget for mycoticins A and B, is described. The key synthetic transformation entails a one-flask, five-component linchpin coupling tactic.
Amos B Smith et al.
Organic letters, 7(15), 3247-3250 (2005-07-16)
[reaction: see text]. A stereocontrolled total synthesis of the neotropical poison-frog alkaloid (-)-205B (1) has been achieved, employing a dithiane three-component linchpin coupling, a one-pot sequential construction of the embedded indolizidine ring, and ring-closing metathesis (RCM) to arrive at the
Amos B Smith et al.
The Journal of organic chemistry, 71(7), 2547-2557 (2006-03-25)
N-Toluenesulfonyl aziridines comprise effective second electrophiles in the solvent controlled three-component linchpin union of silyl dithianes for the stereocontrolled convergent elaboration of protected 1,5-amino alcohols. This tactic, in conjunction with a one-flask sequential cyclization, constitutes an effective general strategy for
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