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Merck
CN

514381

Titanium(III) chloride

≥99.995% trace metals basis

Synonym(s):

Titanium trichloride

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About This Item

Linear Formula:
TiCl3
CAS Number:
7705-07-9
Molecular Weight:
154.23
UNSPSC Code:
26111700
PubChem Substance ID:
24873756
EC Number:
231-728-9
MDL number:
MFCD00011266

Key Documents

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InChI key

YONPGGFAJWQGJC-UHFFFAOYSA-K

InChI

1S/3ClH.Ti/h3*1H;/q;;;+3/p-3

SMILES string

Cl[Ti](Cl)Cl

assay

≥99.995% trace metals basis

form

crystalline

reaction suitability

reagent type: catalyst
core: titanium

mp

440 °C (dec.) (lit.)

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Application

Used for the vapor-phase formation of intermetallic compounds with ultrafine particle size.

pictograms

FlameCorrosion
GHS02,GHS05

signalword

Danger

hcodes

H250,H314

Hazard Classifications

Pyr. Sol. 1 - Skin Corr. 1B

supp_hazards

EUH014

Storage Class

4.2 - Pyrophoric and self-heating hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

Regulatory Information

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Certificates of Analysis (COA)

Lot/Batch Number
MKBN3844V
MKBN2967V
MKBJ4298V
MKBJ9739V
MKBG3063V

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Gnana S Siluvai et al.
Biochemistry, 48(51), 12133-12144 (2009-11-20)
Sco-like proteins contain copper bound by two cysteines and a histidine residue. Although their function is still incompletely understood, there is a clear involvement with the assembly of cytochrome oxidases that contain the Cu(A) center in subunit 2, possibly mediating
C Noubactep et al.
Journal of hazardous materials, 132(2-3), 202-212 (2005-11-08)
The effectiveness of elemental iron (Fe(0)) to remove uranium (U) from the aqueous phase has been demonstrated. While the mitigation effect is sure, discrepancies in the removal mechanism have been reported. The objective of this study was to investigate the
Catalytic oxidation of hydrazo derivatives promoted by a TiCl3/HBr system.
Eyal Drug et al.
Journal of the American Chemical Society, 129(45), 13784-13785 (2007-10-26)
D J Kushner et al.
Analytical biochemistry, 133(1), 116-119 (1983-08-01)
Hydroxamic acid siderophores were observed to be inactivated by exposure to titanium(III) chloride. To study the reaction, a series of eight model hydroxamic acids were prepared and reacted with titanium(III) chloride. The products were shown by ir and NMR comparisons
Yan Zhang et al.
Organic & biomolecular chemistry, 9(13), 4977-4982 (2011-05-21)
N-N bond cleavage in hydrazines is widely used in the preparation of amines and thus occupies a significant place in organic synthesis. In this paper, we report a new method for the reductive cleavage of N-N bonds in hydrazines by
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