518301
4-Fluoro-3-nitrobenzaldehyde
97%
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About This Item
Linear Formula:
FC6H3(NO2)CHO
CAS Number:
Molecular Weight:
169.11
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
Product Name
4-Fluoro-3-nitrobenzaldehyde, 97%
InChI
1S/C7H4FNO3/c8-6-2-1-5(4-10)3-7(6)9(11)12/h1-4H
SMILES string
[O-][N+](=O)c1cc(C=O)ccc1F
InChI key
ILKWFRCNNILIJW-UHFFFAOYSA-N
assay
97%
mp
45-47 °C (lit.)
functional group
aldehyde
fluoro
nitro
Storage Class
13 - Non Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
Regulatory Information
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Solid phase synthesis of vancomycin mimics.
Arnusch CJ and Pieters RJ.
European Journal of Organic Chemistry, 2003(16), 3131-3138 (2003)
S Chowdhury et al.
The Journal of organic chemistry, 66(19), 6257-6262 (2001-09-18)
With the use of S(N)Ar or Ullmann reactions, the synthesis of the first lower-rim aryl ether derivatives of tert-butylcalix[4]arene is reported, as are some of their conformational properties, (1)H NMR spectra, and X-ray crystal structures. The lower-rim aryl pendants reported
K L Kirk et al.
Journal of medicinal chemistry, 29(10), 1982-1988 (1986-10-01)
2-Fluoro-, 4-fluoro-, and 6-fluorophenylephrine (6-FPE) were synthesized from the corresponding fluorinated 3-hydroxybenzaldehydes. New routes to 2-fluoro- and 6-fluoro-3-hydroxybenzaldehydes were developed based on regioselective lithiation of 2- and 4-[(dimethyl-tert-butylsilyl)oxy]fluorobenzene ortho to fluorine. As with norepinephrine and isoproterenol analogues, the adrenergic properties
C A Hutton
Organic letters, 1(2), 295-297 (2000-05-24)
[formula: see text] Numerous biologically active cyclic peptides, such as the antibiotic vancomycin, contain amino acid residues connected through side-chain biaryl or aryl-alkyl ether linkages. Nucleophilic aromatic substitution reactions have recently been shown to provide a general method for the
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