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Merck
CN

519200

3,5-Dibenzyloxybenzyl alcohol

97%

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About This Item

Linear Formula:
(C6H5CH2O)2C6H3CH2OH
CAS Number:
Molecular Weight:
320.38
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
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Product Name

3,5-Dibenzyloxybenzyl alcohol, 97%

InChI

1S/C21H20O3/c22-14-19-11-20(23-15-17-7-3-1-4-8-17)13-21(12-19)24-16-18-9-5-2-6-10-18/h1-13,22H,14-16H2

SMILES string

OCc1cc(OCc2ccccc2)cc(OCc3ccccc3)c1

InChI key

MHHXKZKHZMSINU-UHFFFAOYSA-N

assay

97%

mp

78-81 °C (lit.)

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

Regulatory Information

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The structure and partial synthesis of imbricatine, a benzyltetrahydroisoquinoline alkaloid from the starfish Dermasterias imbricata.
Burgoyne DL, et al.
Canadian Journal of Chemistry, 69(1), 20-27 (1991)
Nathan E Wright et al.
Angewandte Chemie (International ed. in English), 53(13), 3409-3413 (2014-03-29)
Explorations into a series of different approaches for 9-membered carbocycle formation have afforded the first reported example of a 9-exo-dig ring closure via a Au(III)-promoted reaction between an alkyne and an aryl ring as well as several additional, unique Friedel-Crafts-type
B(C6F5)3: an efficient catalyst for reductive alkylation of alkoxy benzenes and for synthesis of triarylmethanes using aldehydes.
Chandrasekhar S, et al.
Tetrahedron Letters, 50(48), 6693-6697 (2009)

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