519367
3,5-Bis(trifluoromethyl)benzenesulfonyl chloride
97%
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About This Item
Linear Formula:
(CF3)2C6H3SO2Cl
CAS Number:
Molecular Weight:
312.62
UNSPSC Code:
12352100
PubChem Substance ID:
EC Number:
254-371-0
MDL number:
Assay:
97%
Product Name
3,5-Bis(trifluoromethyl)benzenesulfonyl chloride, 97%
InChI key
BTRCVKADYDVSLI-UHFFFAOYSA-N
InChI
1S/C8H3ClF6O2S/c9-18(16,17)6-2-4(7(10,11)12)1-5(3-6)8(13,14)15/h1-3H
SMILES string
FC(F)(F)c1cc(cc(c1)S(Cl)(=O)=O)C(F)(F)F
assay
97%
mp
34-38 °C (lit.)
functional group
fluoro
signalword
Danger
hcodes
Hazard Classifications
Skin Corr. 1B
Storage Class
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
226.4 °F - closed cup
flash_point_c
108 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Regulatory Information
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Versatile chiral reagent for the highly enantioselective synthesis of either anti or syn ester aldols.
Corey EJ and Kim SS.
Journal of the American Chemical Society, 112(12), 4976-4977 (1990)
Protein diffusion in porous gel filtration chromatography media studied by pulsed field gradient NMR spectroscopy.
Gibbs SJ, et al.
The Journal of Physical Chemistry, 96(18), 7458-7462 (1992)
Etienne Borré et al.
Beilstein journal of organic chemistry, 6, 1159-1166 (2010-12-18)
Seven novel Hoveyda-Grubbs precatalysts bearing an aminosulfonyl function are reported. Kinetic studies indicate an activity enhancement compared to Hoveyda's precatalyst. A selection of these catalysts was investigated with various substrates in ring-closing metathesis of dienes or enynes and cross metathesis.
Highly enantioselective catalytic thiolysis of prochiral cyclic dicarboxylic anhydrides utilizing a bifunctional chiral sulfonamide.
Takashi Honjo et al.
Angewandte Chemie (International ed. in English), 44(36), 5838-5841 (2005-08-05)
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